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Synfacts 2010(11): 1275-1275
DOI: 10.1055/s-0030-1258807
DOI: 10.1055/s-0030-1258807
Metal-Catalyzed Asymmetric Synthesis and Stereoselective Reactions
© Georg Thieme Verlag
Stuttgart ˙ New York
Asymmetric Conjugate Addition of Arylboronic Acids to Nitroolefins
Z.-Q. Wang, C.-G. Feng, S.-S. Zhang, M.-H. Xu*, G.-Q. Lin*
Shanghai Institute of Organic Chemistry and Shanghai Institute of Materia Medica, P. R. of China
Weitere Informationen
Publikationsverlauf
Publikationsdatum:
21. Oktober 2010 (online)
Significance
This report describes conjugate addition to nitroolefins with high yields and good to excellent enantioselectivities. This method overcomes the previously described difficulties in controlling enantioselectivity for substrates lacking α-substituents.