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Synfacts 2010(10): 1140-1140
DOI: 10.1055/s-0030-1258629
DOI: 10.1055/s-0030-1258629
Synthesis of Materials and Unnatural Products
© Georg Thieme Verlag
Stuttgart ˙ New York
Renaissance of Diels-Alder Reaction of Borylalkenes
H. Yoshida*, M. Mukae, J. Ohshita
Hiroshima University, Higashi-Hiroshima, Japan
Further Information
Publication History
Publication Date:
22 September 2010 (online)
Significance
In view that organoboron compounds play vital roles in modern organic synthesis, the development of efficient and versatile synthetic methods for boryl-containing compounds is highly significant. Herein, the Diels-Alder reaction of trans-borylalkenes with ortho-quinodimethane generated in situ to give boryltetralins is described. Moreover, successful transformation of the tetralins into borylnaphthalenes via an oxidative aromatization is disclosed.