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Synfacts 2010(10): 1179-1179
DOI: 10.1055/s-0030-1258600
DOI: 10.1055/s-0030-1258600
Metal-Mediated Synthesis
© Georg Thieme Verlag
Stuttgart ˙ New York
Rhodium-Catalyzed Pauson-Khand-Type Reaction
J. H. Park, Y. Cho, Y. K. Chung*
Seoul National University, Korea
Further Information
Publication History
Publication Date:
22 September 2010 (online)
Significance
This work reports a rhodium-catalyzed Pauson-Khand-type reaction in a one-pot procedure. Alcohols are used as carbon monoxide source, whereby the dehydrogenation, decarbonylation, and metal carbonyl complex formation take place in a cascade reaction which requires only a single catalyst species.