DOI:
10.1055/s-00000084
Synthesis
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References
Wiemer et al. have demonstrated
extensively the base-catalysed rearrangement of vinyl phosphates
to the corresponding β-keto phosphonates; a process driven
under thermodynamic control by the formation of a stabilised anion.
For an example, see: Calogeropoulou T, Hammond GB, Wiemer DF,
J.
Org. Chem.. 1987; 52 4185
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