DOI:
10.1055/s-00000083
Synlett
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This is true as long as the R substituent
shown in Scheme 1 is an aliphatic group. It has been shown that
activated propargylic alcohols bearing aromatic substituents isomerize
to the corresponding alkenoates in the presence of tertiary amines: Sonye JP, Koide K,
Org.
Lett.. 2006; 8 199 ;
and references cited therein
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