DOI: 10.1055/s-00000131

Synfacts

Issue 03 · Volume 20 · March 2024 DOI: 10.1055/s-014-59119

Synform

  • A036

    SYNFORM ISSUE 2024/03

    • Synthesis of Natural Products

  • z0223

    All PDFs of this category

  • 0223

    Total Synthesis of (–)-Cephalocyclidin A

  • 0224

    Synthesis of Calyciphylline A-Type and Macrodaphniphyllamine-Type Alkaloids

  • 0225

    Total Synthesis of (+)-Rhodomollin A

  • 0226

    Enantioselective Total Synthesis of (+)-Euphorikanin A

  • 0227

    Synthesis of (–)-Garryine

  • 0228

    Total Synthesis of (+)-Arboduridine

  • 0229

    Total Synthesis of (–)-Magellanine

    • Synthesis of Heterocycles

  • z0231

    All PDFs of this category

  • 0231

    Strained exo-Methylene Heterocycles as Dipolarophiles: Synthesis of Unexplored Spiroisoxazolines

  • 0232

    Multicomponent Synthesis of Tetrahydroisoquinolines

  • 0233

    Synthesis of 2-Alkylmethyl Pyrroline Derivatives

  • 0234

    Sc(OTf)3‑Catalyzed Cycloadditions for the Synthesis of Substituted Indolines

  • 0235

    Gram-Scale, Modular Access to C2-Bis(Oxazoline) Ligands

  • 0236

    Multicomponent Synthesis of Quinolines via Hydrogen-Transfer Reaction

  • 0237

    A Highly Diastereoselective Synthesis of Sulfur-Containing Unnatural Amino Acids

  • 0238

    Efficient, Epimerization-Free Solid-Phase Peptide Synthesis

  • 0239

    Versatile Synthesis of Tertiary and Heterocyclic and Aromatic Amines

  • 0240

    Practical and Efficient Access to Multifunctional BCPs

  • 0241

    Synthesis of 2,5-Disubstituted Pyridines via Gold(I)-Catalyzed Cycloisomerization of 1-Bromoalkynes

  • 0242

    Nitrogen Atom Insertion into Arenols in the Synthesis of Benzazepines

  • 0243

    Palladium-Mediated Synthesis of 3-Methylindoles Under Mild Conditions

    • Synthesis of Materials and Unnatural Products

  • z0245

    All PDFs of this category

  • 0245

    2-Center-3-Electron π-Bond without a σ-Bond

  • 0246

    Aryne-Activated Smiles Rearrangement of Anilines

  • 0247

    Hydroaminoalkylation of Polybutadiene

  • 0248

    Iterative Binomial Synthesis of Monodisperse Conjugated Polymers

  • 0249

    Alternating Poly(Lactic-co-Glycolic Acid) from Racemates

  • 0250

    Phenanthridines from Oxime Esters

  • 0251

    1,3-Azaphospholes

  • 0252

    Chloride-Directed Enantioselective C(sp2)–H Borylation

  • 0253

    Macrocycle Skeletal Rearrangement of a Cationic Borane

  • 0254

    Facile Synthesis of Indolocarbazole from Indoles

  • 0255

    Heptagon Annulation via C−H Activation

  • 0256

    A Neutral 2π-Aromatic Si2B2 Ring

    • Metals in Synthesis

  • z0257

    All PDFs of this category

  • 0257

    Wittig-Type E-Selective Olefination of Imines with Vinyl Boronate Esters Under Copper Hydride Catalysis

  • 0258

    Cyanation of Allenes via Copper-Catalyzed Site-Selective C(sp2)–H Hydrogen Atom Abstraction

  • 0259

    Regioselective C(sp³)–H Activation of Cyclic Aliphatic Acids: Synthesis of Unsaturated Bicyclic Lactones

  • 0260

    Acylation of Unactivated C(sp3)–H Bonds with Acyl Azolium Reagents under Photoinduced Cerium Catalysis

  • 0261

    Rhodium Catalyzed Three-Component Coupling Annulation of 2-Aryloxazolines

  • 0262

    Asymmetric Synthesis of Eight-Membered N-Hetero-cycles by Palladium-Catalyzed (4+4) Cycloaddition

  • 0263

    Divergent Multicomponent Fluoroalkylative Carbonylation of 1,3-Enynes Under Palladium Catalysis

  • 0264

    An Electroreductive Strategy for the Hydroxy Fluorosulfonylation of Alkenes

  • 0265

    Regioselective C(sp2)–H Borylation of (Hetero)Arenes under Cobalt Catalysis

  • 0266

    Iron-Catalyzed Coupling of Allylic Dithianes with Alkynylsilanes Involving a Dithiane Rearrangement

  • 0267

    Tetracyclic Cycloheptanols Synthesis via Rhodium-Catalyzed Cascade Reaction

  • 0268

    Cobalt-Catalyzed Synthesis of Amines via Nitriles Electrohydrogenation

  • 0269

    Hiyama Cross-Coupling of gem-Difluoroalkenes: Stereoselective Synthesis of Tetrasubstituted Olefins

  • 0270

    Copper-Catalyzed Suzuki–Miyaura Cross-Couplings of Unactivated Alkyl Halides

  • 0271

    Photoenzymatic Catalyzed Coupling of Amino Acids with Vinylpyridines

  • 0272

    Carbonylation/Amination of Alkylidenecyclopropanes Towards Eight-Membered Benzolactams

  • 0273

    Electrophotochemical Decarboxylative Vinylation of Carboxylic Acids under Dual Cerium and Nickel Catalysis

  • 0274

    Enantioselective α-Alkylation of Enolizable Ketones with Alkyl Iodides under Bimetallic Nickel Catalysis

  • 0275

    Nickel-Catalyzed Silylalkylation of Unactivated Terminal Alkenes

  • 0276

    Enantioselective Synthesis α-Gem-Difluorinated Alcohols via Rh(III)-Catalyzed Transfer Hydrogenation

  • 0277

    Asymmetric Hydroacylation of Internal Olefins and Aldehydes

  • 0278

    Alkyllithium- and Magnesium Salt-Assisted 1,1- and 1,3-Aminoboration of Alkenes under Nickel Catalysis

  • 0279

    Iridium Photoredox-Catalyzed Nitrative Difunctionalization of Alkenes

  • 0280

    Sequential Cu-Borylation Strategy for a Stereodivergent Synthesis of Functionalized Cyclohexanones

  • 0281

    Synthesis of Linear Aliphatic Amides via Rh-Catalyzed Hydroamidation of Internal Olefins

  • 0282

    Iron-Photocatalyzed C(sp2)–H Trifluoromethylation of (Hetero)Arenes with Trifluoroacetates

  • 0283

    The First Use of Aryltrimethylammonium Salts in Nickel-Catalyzed Suzuki Cross-Couplings

    • Polymer-Supported Synthesis

  • z0285

    All PDFs of this category

  • 0285

    Intramicellar Pd-Catalyzed β-Arylation of Thiophenes

  • 0286

    Oxidative Coupling of Amines Using a 4-Nitrophenyl­acethylene-Functionilzed Cu2O Crystal

  • 0287

    A Spirobifluorene-Based COF for Photo-Induced Nickel-Catalysed Amination of Aryl Halides

  • 0288

    Photocatalytic Synthesis of 1,3-Diarylated Imidazo[1,5-a]pyridines with Carbon Nitride

  • 0289

    Photocatalytic Dehalogenative Deuteration and Hydrogenation of Halides by a Chromium-Based MOF

  • 0290

    Nitriles and Amides Synthesis from 1,2-Diols by N-Doped Porous Carbons

  • 0291

    Borylation of Alkyl and Aryl Halides Using CeO2 Nanorods

  • 0292

    Preparation of Alkylamines from Alcohols and Carbonyl Compounds through Reductive Amination

  • 0293

    Minisci-Type Reactions Promoted by a Zirconium-Phenazine MOF

  • 0294

    Dehydrogenative Coupling of Organosilanes with Alcohols by a Single-Atom Gold(I) Catalyst

  • 0295

    Dehydrogenative Cross-Coupling of P(O)H and Thiols by a Polyoxomolybdate Photocatalyst

    • Organo- and Biocatalysis

  • z0297

    All PDFs of this category

  • 0297

    Metal-free meta-Selective C–H Amination of Arenes

  • 0298

    Acid-Catalyzed Nitromethane Activation for the Synthesis of Amides and Nitriles

  • 0299

    Enzymatic C–H Amidation toward Stereoselective Construction of β-, γ- and δ-Lactams

  • 0300

    Enantioselective C−C Bond Insertion into Aldehydes via Oxazaborolidinium Catalyzed 1,2-Acyl Shift

  • 0301

    Biocatalytic Approach for the Synthesis of Lactones via Carbene C–H Insertion

  • 0302

    Photoenzymatic Hydrosulfonylation of Olefins Initiated by Single Electron Oxidation

  • 0303

    VANOL-Derived Imidodiphosphorimidate-Catalyzed Bromospiroketalization

  • 0304

    Stereoselective α-Benzylation of Cyclic Ketones via Chemoenzymatic Cascade

  • 0305

    Asymmetric Cyclizations Catalyzed by Chiral Boryl Radicals

  • 0306

    Brønsted Acid Catalyzed Aromatization-Enabled Umpolung of Imines

    • Innovative Drug Discovery and Development

  • z0307

    All PDFs of this category

  • 0307

    A Rhodium-Catalyzed “Hook-and-Slide” Homologation of Amides

  • 0308

    HIV-1 Non-Nucleoside Reverse Transcriptase Inhibitors That Prematurely Activate Protease Causing Cell Death

  • 0309

    Chemoenzymatic Syntheses of Fluorine-18-Disaccharides to Image Bacterial Infection

  • 0310

    Facile Access to Bioactive Piperidine-γ-Butyrolactones

  • 0311

    Synthesis, Structural Validation, and SAR of Antifungal Fusaramin

  • 0312

    Tryptamine Derivatives of Norpsilocin Induce Psychedelic-Like Responses in Mice

  • 0313

    Novel Synthesis of Levadopa Improves Efficiency and Eliminates Use of Pyrophoric Raney Nickel

  • 0314

    Selective Installation of C1-C3 Fluorocarbons to Aldehydes

  • 0315

    Multikilogram Birch Reduction and Evaluation of Alternative Synthetic Routes to a Ketalized Cyclohexene Derivative

  • 0316

    Accessing 2-Aminophenol Derivates Using Triplet-State Nitro(hetero)arenes and Copper Photocatalysis

  • 0317

    Development of a Continuous Flow Process for Photoredox Decarboxylative Fluorination

  • 0318

    A Chiral Amide Directing Group for Ruthenium-Catalyzed Asymmetric C–H Activation

  • 0319

    Matteson Homologation-Based Total Synthesis of Meliponamycin A

  • 0320

    Discovery of the Selective KRAS G13D Inhibitors Derived from the Scaffold of KRAS G12C Inhibitor

  • 0321

    Photo-Uncaging of a Microtubule Depolymerizer Reduces Tumor Volume in a Mouse Model

  • 0322

    Photomediated Deaminative Generation of Tertiary Anions

    • Peptide Chemistry

  • z0323

    All PDFs of this category

  • 0323

    Peptide Cyclization of Unprotected Peptides with Cysteine at C-Terminal

  • 0324

    Boronic Acid-Catalyzed Peptide Bond Formation from Serine- and Threonine-Derived Inert Esters

  • 0325

    Metal-Free Synthesis of α‑Tertiary Amino Acid Derivatives via Photoinduced Cross-Coupling

  • 0326

    Unnatural Peptide Synthesis through Rh(III)-Catalyzed Diastereoselective Ligation with Three Components

  • 0327

    Isothiourea-Catalyzed Conjugate Addition to Form Proline Derivatives

  • 0328

    Palladium-Catalyzed Photoinduced Alkylation for Glycine Derivatives

  • 0329

    Direct Amidation of Unprotected Amino Acids Mediated by Hexylsilane

  • 0330

    Co-Catalyzed Asymmetric Aza-Barbier Reaction: A Useful Method for α-Tertiary Amino Ester Synthesis

  • 0331

    Direct Synthesis of γ-Amino Acid Derivatives via Cobalt-Catalyzed Aminoalkylative Carbonylation of Alkenes

  • 0332

    Palladium-Catalyzed Cross-Coupling for the Synthesis of Pyridyl Amino Acids

    • Flow Chemistry

  • z0333

    All PDFs of this category

  • 0333

    Continuous-Flow Heterogeneous Rhodium-Catalyzed Asymmetric Hydroacylations