DOI: 10.1055/s-00000131

Synfacts

Issue 11 · Volume 18 · November 2022 DOI: 10.1055/s-012-55462

Synform

  • A167

    SYNFORM ISSUE 2022/11

    • Synthesis of Natural Products

  • z1167

    All PDFs of this category

  • 1167

    Synthesis of (–)-10-Deoxydaphnipaxianine A, (+)-Daphlongamine E and (+)-Calyciphylline R

  • 1168

    Total Synthesis of Indole Alkaloid (+)-Alstonlarsine A

  • 1169

    Total Synthesis of the Grayanoid (+)-Mollanol A

  • 1170

    Synthesis of (+)-Mutilin

  • 1171

    Total Syntheses of (–)-Napelline

  • 1172

    Total Synthesis of (+)-Aberrarone

  • 1173

    Total Synthesis of (–)-Ircinol A, (+)-Ircinal A

    • Synthesis of Heterocycles

  • z1175

    All PDFs of this category

  • 1175

    Selective N2-Alkylation of 1H-Azaindazoles

  • 1176

    Synthesis of 6-Phenanthridines by Photocatalytic Deoxygenation of Alcohols

  • 1177

    Synthesis of Versatile Enantiopure Morpholine Fragments from Chiral-Pool Starting Materials

  • 1178

    Multicomponent-Reaction-Triggered Cascade Approach to Functionalized Fused 2,6-Diketopiperazines

  • 1179

    Design and Synthesis of Azaborine-Based Steroid Mimics

  • 1180

    Silver-Catalyzed Synthesis of Densely Functionalized gem-Difluorinated Molecules

  • 1181

    Mechanistic Insights into Light-Mediated C–H Functionalization of 2-Phenylpyridines

  • 1182

    Furans by Rhodium-Catalyzed Tandem Cyclization of Acrylic Acids

  • 1183

    Microwave-Assisted Synthesis of Tertiary Amines from Carbamates

  • 1184

    Synthesis of Spiro[furan-2,1′-isoindolin]-3′-ones by Intramolecular Sequential Prins and Ritter Reactions

  • 1185

    Nickel-Mediated C(sp2)–C(sp3) Cross-Couplings

    • Synthesis of Materials and Unnatural Products

  • z1187

    All PDFs of this category

  • 1187

    Transition-Metal Catalyzed Chain-Growth Conjugated Polymers

  • 1188

    Bisurea-Functionalized Tetraazaperylene

  • 1189

    Traceless Template for All-benzene Catenane

  • 1190

    Expanded Radialenes and Their Aromatic Dianions

  • 1191

    Silver and Gold Go Hand in Hand

  • 1192

    Metathesis of Electron-Deficient Alkenes

  • 1193

    Biomimetic Synthesis of Benzothiophene Sulfoxides

  • 1194

    Acenes Fused with Azulene

  • 1195

    Highly Strained Naphthalenonaphthalenophane

  • 1196

    Ring-Fused Hexameric Perylene Diimide

  • 1197

    Ester Exchange as Pivot to Block Polyolefins

  • 1198

    A Triplet Ground State Kekulé Hydrocarbon

    • Metals in Synthesis

  • z1199

    All PDFs of this category

  • 1199

    Palladium-Catalyzed Butafulvene Synthesis

  • 1200

    Iridium-Catalyzed Enantioselective and Diastereodivergent Propargylic C(sp3)–H Allylation

  • 1201

    1,1-Difunctionalization of Terminal Alkenes to Chiral Allylboronates under Nickel Catalysis

  • 1202

    Enantioselective Synthesis of gem-Diarylmethylsilanes via a Three-Component Coupling Reaction

  • 1203

    Accessing Cyclopropenium Cations via a Rh-Catalyzed Oxidative [2+1] Reaction

  • 1204

    Copper-Catalyzed Vinylogous and Bisvinylogous Asymmetric Propargylic Substitution

  • 1205

    Stereodivergent Cross-Coupling of Aryl Halides with Redox-Active Imines

  • 1206

    Enantioconvergent Benzylic C–H Azidation of Indolines Enabled by a Cationic Manganese Salen Catalyst

  • 1207

    Palladium-Catalyzed Diolefination/Cyclization Reaction of o-Toluidine with Acrylates

  • 1208

    Synthesis of Isocytosine Analogues via Palladium-Catalyzed Ring-Opening/Arylation/Cyclization Cascade

  • 1209

    Copper(I)-Catalyzed Kinugasa/C–C Coupling Domino Reaction Towards Spirocyclic Oxindoles

  • 1210

    Turning Aliphatic Carboxylic Acids into Fluorides under Iron Catalysis and Visible Light

  • 1211

    Pd-Catalyzed Synthesis of Diaryl Difluoromethanes from Aryl Halides and Aryldifluoromethyl Trimethylsilanes

  • 1212

    Palladium-Catalyzed Cross-Coupling of Silicon-Masked Diazenyl Anions and (Hetero)Aryl Halides

  • 1213

    Cu-Catalyzed Borylallylation of in situ Generated Imines – ­Lewis Base Additive Prevents Direct C–N Coupling

  • 1214

    Photoinduced Ring Opening of Cycloalkanols under Dual Organophotoredox and Copper Catalysis

  • 1215

    Nickel-Catalyzed Dearomative Arylcyanation of Indoles

  • 1216

    Palladium-Catalyzed, Directing Group-Enabled Perfluoroselenolation of Vinylic C–H Bonds

  • 1217

    Let’s Do The Twist: Atroposelective Suzuki–Miyaura Cross-Coupling to Access Axially Chiral Biphenols

  • 1218

    Nickel-Catalyzed Enantioselective Tandem Aza-Heck Cyclization and Cross-Coupling with Alkyl Iodides

  • 1219

    Modular Palladium-Catalyzed Synthesis of Highly Conjugated Benzophosphole Derivatives

  • 1220

    A Bench-Stable Bismuth(III) Precursor Promotes theα-Arylation of 1,3-Diketones with Arylboronic Acids

  • 1221

    The Hirao Reaction: Palladium-Catalyzed Cross-Coupling of Dialkyl Phosphites with Aryl Halides

  • 1222

    Copper-Catalyzed Conjugate Borylation of Enones

    • Polymer-Supported Synthesis

  • z1223

    All PDFs of this category

  • 1223

    Aerobic Oxidation of Alcohols and Sulfides on Todorokite-Type Manganese Oxide Nanoparticles

  • 1224

    Michael Addition of Aldehydes to Nitrostyrenes on a Tetrahydropyran-Based Dipeptide Catalyst

  • 1225

    Amination and Trifluoroethylation of Fullerenes Promoted by Subphthalocyanine Capsules

  • 1226

    Diastereoselective Hydrogenation of Arenes and Pyridines Promoted by a Ru-Phenanthroline Catalyst

  • 1227

    Oxidation of Benzylic C–H Bonds with a Single-Atom-Like Zinc Catalyst

  • 1228

    Preparation of α-Hydroxy Carboxylic Acids by Carboxylation of Aldehydes on a Nickel(II) Catalyst

  • 1229

    Synthesis of 3,4-Dihydro-2H-Pyrroles by a Nickel-Catalyzed Hydrogenative Cyclization

  • 1230

    Heterogeneous Photocatalytic Synthesis of Functionalized Dihydropyrazoles from Hydrazones

  • 1231

    Photocatalytic Hydrogenation of Olefins and Nitro-benzenes with Al–H2O on Pd-Doped Carbon Nitride

  • 1232

    Asymmetric Alkylation of α,β-Unsaturated Ketones or Imines on a Polymeric Copper Catalyst

  • 1233

    Nanohybrid Photocatalyst for the Synthesis of Aryl Carbonyl Compounds and Benzimidazoles

    • Organo- and Biocatalysis

  • z1235

    All PDFs of this category

  • 1235

    Thioxanthone-Catalyzed Single-Step Synthesis of β- and γ-Amino Acid Derivatives

  • 1236

    Supramolecular Capsule Emulates Enzymatic Proton-Wire Mechanism in β-Selective O-Glycosylations

  • 1237

    Biocatalytic Double- and Triple-Cascades Permit Highly Stereoselective Syntheses of Cyclohexene Derivatives

  • 1238

    Photocatalytic Functionalization of Nonactivated C(sp3)–H Bonds

  • 1239

    Photoredox-Catalyzed Imino Alkylation of Electronically Diverse Alkenes with Bifunctional Oxime Esters

  • 1240

    N-Arylphenothiazine-Catalyzed Cross-Coupling of Allyl Bromides with Arylboronic Acids

  • 1241

    Organocatalytic Construction of Heterobiaryl Atropisomers via Vinylidene–Quinone Methides

  • 1242

    Disulfide Reagent for Catalytic Asymmetric α-Alkylsulfenylation of Carbonyl Compounds

  • 1243

    Organocatalytic On-Water System for the Synthesis of α-Tertiary Amines

  • 1244

    Intermolecular Organosulfide-Catalyzed Difunctionalization of Allylic Sulfonamides

  • 1245

    Enzymatic Site-Selective and Atroposelective Bromination of 3-Aryl-4(3H)-Quinazolinones

  • 1246

    Organocatalytic Cationic Polymerization toward High-Molecular-Weight Poly(2,3-Dihydrofuran)

    • Innovative Drug Discovery and Development

  • z1247

    All PDFs of this category

  • 1247

    Kinetic Target-Guided Synthesis of ERAP2 Inhibitors

  • 1248

    α-Synuclein Proaggregators via C–H Arylation

  • 1249

    A Non-Peptidic Protease Inhibitor for HIV Treatment

  • 1250

    Lomaiviticin A Monomer – Not as Cytotoxic as the Dimer

  • 1251

    Synthesis and Reevaluation of (+)- and (−)-Collybolide as kappa-Opioid Receptor Agonists

  • 1252

    Dual-Controlled Tumor Imaging using an Enzyme-Responsive and Photoactivated Probe

  • 1253

    Shortest Synthesis of Lysergol and its Binding to 5-HT1/2Receptors

  • 1254

    Dynamic Kinetic Resolution of Axially Chiral MRTX1719

  • 1255

    A Medicinal Chemist's Guide to Decarboxylative Cross-Couplings

  • 1256

    Atroposelective Annulations Afford Darobactin A

  • 1257

    Targeting KRAS G12R with α,β-Diketoamides

  • 1258

    Selective CYP11B1 Inhibitor Development via an Enantiomer Discrimination

  • 1259

    Application of Continuous Processing for a Scalable High-Temperature Racemization

  • 1260

    Design of a GPCR Antagonist from Agonist Scaffold

  • 1261

    A Candidate for Potential Treatment of Heart Failure with Preserved Ejection Fraction

  • 1262

    An Ene-reaction Ene-ables an α-Kainic Acid Synthesis

    • Peptide Chemistry

  • z1263

    All PDFs of this category

  • 1263

    Palladium-Catalyzed C(sp3)–H Arylation of Cyclic Peptides

  • 1264

    C–H Alkylation for the Synthesis of Tetrasubstituted Amino Acid Derivatives

  • 1265

    Primary Amine–Thiourea-Catalyzed Enantioselective Alkylation of Cyclic Ketones

  • 1266

    Functionalization of Aspartic or Glutamic Acids through Photoinduced Decarboxylation

  • 1267

    Iridium-Catalyzed Photochemical [2+2]-Cycloaddition of Dehydroamino Acids with Styrenes

  • 1268

    Synthesis of α-Amino Acids by Enantioselective Carbene Insertion

  • 1269

    Potassium Fluoride-Mediated Deprotection of Fmoc-Amino Acid Esters: One-Pot Peptide Synthesis

  • 1270

    Chiral Calcium Phosphate-Catalyzed Amination of β-Keto Esters

    • Flow Chemistry

  • z1271

    All PDFs of this category

  • 1272

    Synthesis of α-Aminoamides by a Photocatalytic Continuous-Flow Reaction

  • 1273

    Scalable Photoalkylation of Carbohydrates in Flow with a Sustainable Organocatalyst

  • 1274

    Hydrogen-Transfer Reaction Using Packed-Column Catalysts in Flow

  • 1275

    Photochemical Approach for the Synthesis of Tetrahydroimidazo[1,2-a]pyridine 1-Oxides