Synfacts

Issue 01 · January 2017

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SYNFORM ISSUE 2017/01 FREE ACCESS

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Synthesis of Natural Products and Potential Drugs
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Synthesis of an Atropisomeric HIV Integrase Inhibitor FREE ACCESS

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0002
Synthesis of UM171

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0003
Synthesis of (±)-Atropurpuran FREE ACCESS

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0004
Enantioselective Synthesis of Efavirenz

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0005
Synthesis of (–)-Cyclosmenospongine

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0006
Synthesis of (±)-Morphine

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0007
Synthesis of Swinholide A

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0008
Manufacturing Route to Avibactam

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0009
Synthesis of Tofogliflozin Hydrate

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0010
Crystallization-Induced Dynamic Resolution of a Dibenzoazepinone

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0011
α-Arylation of Malonate Derivatives via Oxidative Catalysis

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0012
Synthesis of (–)-Englerin A

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0013
Synthesis of (+)-Hinckdentine A

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0014
Synthesis of Nisoxetine

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0015
Synthesis of Araiosamines

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0016
Synthesis of VPC01091

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0017
Synthesis of Amino-Carbasugars

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Synthesis of Heterocycles
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0019
Synthesis of 3,3-Diaryloxetanes from Oxetanols by a Friedel–Crafts Reaction

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0020
Selective Functionalization of Pyridines via Their Phosphonium Salts

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0021
Synthesis of Epoxides by a Darzens Reaction and Vicarious Nucleophilic Substitution

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0022
Ytterbium(III)-Catalyzed Synthesis of Epiminodibenzo[b,f][1,5]diazocines

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0023
Synthesis of Pyrrolidines, Pyrroles, and Carbazoles by Iridium Catalysis

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0024
Enantiospecific Access to Bicyclic Morpholines and Piperazines

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0025
Rhodium(III)-Catalyzed Synthesis of Benzo[a]carbazoles

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0026
Synthesis of Azetidines by Ring Opening and Closing of Cyclopropanes

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0027
Synthesis of Substituted Pyrroles from α-Iminodiazoacetates

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0028
Enantioselective Synthesis of Spirooxindole 2H-Azirines

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0029
Photochemical [2+2]-Cycloaddition Route to Enantiomerically Pure Oxetins

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Synthesis of Polyfunctional Pyrrolidines, Pyrrolines, and Thioxopyrrolidines

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Synthesis of Materials and Unnatural Products
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One-Pot, Why Not?

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0032
Two Tastes of Propargyl Acetates

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0033
Dancing with Sulfur

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0034
Mutant Nanographenes

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0035
An Approach to Zigzag Carbon Nanobelts

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0036
Function by Switching: Heterodiazocines

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0037
A Trophy for BOPHYs

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0038
Two N-Tosyl Hydrazones Joined Together by the Hand of Sulfur

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0039
Alkyne Metathesis Macrocyclization and Copper-Free Click Reactions

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0040
One ‘S’tone, Two Bird‘S’

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0041
Supercharged Snowflake

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0042
Reversible Dimerization and Polymerization of a Janus Diradical

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Metal-Catalyzed Asymmetric Synthesis and Stereoselective Reactions
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0043
Palladium-Catalyzed Asymmetric Synthesis of α,α-Disubstituted Allylic N-Arylamines FREE ACCESS

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0044
Magnesium-Catalyzed Desymmetrization of meso-Aziridines with Hydroxylamines

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0045
Cyclohexenylamines and Cyclohexenols by Rhodium-Catalyzed Cycloaddition FREE ACCESS

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0046
Silver-Catalyzed Enantioselective Nitroso Aldol Reaction of Nitrosoarenes

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0047
Palladium-Catalyzed Asymmetric Alkenylation of Trisubstituted Alkenols

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0048
Rhodium-Catalyzed Conjugate Addition Towards Chiral Thioflavanones

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0049
Zinc(II)-Catalyzed Asymmetric Aza-Friedel–Crafts Reaction of Ketimines

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0050
Nickel-Catalyzed Asymmetric Allenyl Claisen Rearrangement

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0051
Gold-Catalyzed Tandem Cycloisomerization/Hydrogenation

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0052
Asymmetric Allylic Alkylation Towards Dihydrocoumarins and Isochromanones

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0053
Palladium-Catalyzed Asymmetric Synthesis of Indolines by C(sp³)–H Arylation

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0054
New Chiral Cyclic Sulfinamide–Olefin Ligands for Asymmetric 1,4-Additions

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0055
Asymmetric Iridium(I)-Catalyzed Diene Hydrohydroxymethylation

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0056
Rhodium Pincer Complex Catalyzed Direct Alkynylation of Ketones

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0057
Copper(I)–NHC Catalyst for the Stereo-selective Semihydrogenation of Alkynes

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0058
Enantioselective Palladium-Catalyzed Synthesis of 3-Indolyl Methanamines

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0059
Nickel-Catalyzed Synthesis of Thiochromanyl-Spirooxindoles

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0060
Ruthenium/Palladium Dual-Metal Catalysis for Oxindole Synthesis

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0061
Enantioselective Rhodium-Catalyzed Arylation Generating Triarylmethanes

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0062
Iridium-Catalyzed Asymmetric γ-Alkynylation of α,β-Unsaturated Amides

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0063
Nickel(0)-Catalyzed Stereoselective Synthesis of Vinylcyclopropanes

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0064
Enantioselective Silver-Catalyzed [3+2] Cycloaddition

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0065
Asymmetric Synthesis of β-Hydroxy α-Amino Acid Derivatives

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0066
Copper-Catalyzed Ring Opening of Cyclopropanes with Inversion

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0067
Rhodium(II)-Catalyzed Asymmetric Cyclopropanation

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0068
Oxidative Fragmentation Follows an Asymmetric Hydrogenation

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0069
Iridium-Catalyzed Asymmetric Reduction of Pyridinium Salts

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0070
Asymmetric Allenylation of Sulfonylimines Catalyzed by Rhodium

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Metal-Mediated Synthesis
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0071
Ring-Forming Thioboration of C–C π-Bonds FREE ACCESS

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0072
Synthesis of α-Trifluoromethylated Ketones

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0073
Synthesis of β-Boryl-α-Aminosilanes

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0074
Synthesis of α-Sila Benzamides

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0075
Aldol Reactions of Azetidin-2-one

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0076
Asymmetric Catalysis of Indoles and Dihydroisoquinolines via Allylboration

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0077
Rhodium(I)-Catalyzed Coupling with Arylboronic Acids

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0078
Catalytic Hydroboration of Nitriles and Imines

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0079
Cobalt-Catalyzed C(sp²)–H Borylation

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0080
Nucleophilic Tetrafluoroethylation

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0081
C–O Bond Activation

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0082
ortho-C–H Functionalization

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0083
Diaryl Ketones by Nickel Catalysis

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0084
Suzuki–Miyaura Cross-Coupling of Amides via Cooperative Catalysis

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0085
C–F Bond Activation

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Organo- and Biocatalysis
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0087
Allylboration of Aldehydes by Immobilized TRIP FREE ACCESS

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0088
Asymmetric Oxidative Dearomatization/Oxa–Michael Addition Sequence

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0089
Catalytic Asymmetric Aminoalkynylation of Arenes

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0090
Regiodivergent Chlorination of Phenols Controlled by a Lewis Base Catalyst

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0091
Regioisomeric Fluorolactonization via Hypervalent Iodine Catalysis

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0092
Electrostatically Enhanced Phosphoric Acids in Brønsted Acid Catalysis

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0093
Enantioselective Aza–Sakurai Cyclization

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0094
Organocatalytic Asymmetric Vinylogous Prins Cyclization

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0095
Enantioselective Catalytic Thioacetalization of Aldehydes

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Polymer-Supported Synthesis
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0097
Conversion of Arylboronic Acids into Phenols with Biogenic Cu₂O Nanoparticles

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0098
Photocatalytic Click Chemistry with Copper Oxide Doped Semiconductors

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0099
Spirocyclization of Alkyne-Tethered Aromatics with Silver Nitrate/Silica FREE ACCESS

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0100
In–Co(Porphyrin) Metal–Organic Framework Catalyzed Hydration of Terminal Alkynes

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0101
Olefin Metathesis with Metal–Organic Framework Adsorbed Ruthenium Complexes

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0102
Nanoorganocatalyst for the Synthesis of 2-Amino-4H-chromene-3-carbonitriles

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0103
Olefin Hydrogenation with Mesoporous Silica-Supported Pd–Fe Nanoreactors

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0104
Copper-Catalyzed Synthesis of 2-Aryl-1-imidazo[1,2-a]pyridin-3-ylethane-1,2-diones

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0105
Thiol-Grafted Cellulose Paper for Copper-Catalyzed Click Reactions

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0106
Supported Copper Catalyst for N-Arylation Reactions and Click Chemistry

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0107
Palladium Nanoparticle Catalyzed Hydrogenation of Quinolines and Quinoxalines

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0108
Synthesis of 1-Amidoalkyl-2-naphthols with Graphene Oxide

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0109
Sulfoximinocarbonylation of Aryl Halides with Palladium/Carbon

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0110
Decarboxylative Arylation and Carbonylative C–C Coupling with Copper Nanoparticles

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0111
FeCl₃/SiO₂-Catalyzed Condensation of 1,2-Diaminobenzenes with β-Keto Carbonyls

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0112
Tetrahydropyranylation of Alcohols Catalyzed by an Acidic Ionic Liquid

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0113
Hydroamination of Alkynes with Gold Nanoparticles/Titania

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