Synfacts

Issue 06 · June 2016

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Synform
A79
SYNFORM ISSUE 2016/06 FREE ACCESS

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Synthesis of Natural Products and Potential Drugs
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0547
Synthesis of an 11-β-HSD-1 Inhibitor via Asymmetric Methallylation FREE ACCESS

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0548
Synthesis of Tofogliflozin

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0549
Total Synthesis of Indole Alkaloids FREE ACCESS

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0550
Synthesis of Rivaroxaban

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0551
Synthesis of (+)-Piperarborenine B

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0552
Synthesis of (–)-Mandelalide A

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0553
Synthesis of CPI-0610

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0554
Synthesis of MK-8831

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0555
Asymmetric Synthesis of (+)-Phorbol

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0556
Synthesis of Citalopram

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0557
Synthesis of Escitalopram

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0558
Asymmetric Synthesis of (–)-Nakadomarin A

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0559
Synthesis of Cryptocaryol A

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0560
Synthesis of Huprine Derivatives

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0561
Synthesis of Daclatasvir by C–H Activation

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0562
Synthesis of Lundurines A–C

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Synthesis of Heterocycles
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0563
Benzofurans from β-Pyrones and Phenols

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0564
4-Bromo-1,2-dihydroisoquinolines from ortho-Triazolylbenzyl Bromides

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0565
Lewis Base-Catalyzed Dynamic Kinetic Resolution of Azole Esters FREE ACCESS

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0566
Synthesis of Indazoles by Oxidative N–N Bond Formation

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0567
Benzoxazocindiones from Phthalic Acids and Cyclic Sulfamidates

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0568
Palladium-Catalyzed Three-Component Synthesis of 2-Aroylbenzofurans

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0569
Tetrahydronaphthyridines by a Radical Pictet–Spengler Reaction

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0570
Pyrrolizidines and Indolizidines by Photooxidation of Furylalkylamines

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0571
Enantioselective Synthesis of Piperidines from Pyridines

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0572
Three-Component Synthesis of Pyrazolo [3,4-d]thiazolo[3,2-a]pyrimidines

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0573
Triazole–Gold Catalyzed Approach to Substituted 2,3-Dihydrooxepines

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0574
Copper-Catalyzed C–N Coupling/Madelung Synthesis of Indoles

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0575
Direct Ketone Synthesis by Hetaryl Grignard Addition to Carboxylic Acids

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Synthesis of Materials and Unnatural Products
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0577
PET-RAFT + ROP = Copolymers!

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0578
Coplanar Triply Linked 2H-Corrole Dimers

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0579
All-Carbon Carbodicarbene FREE ACCESS

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0580
Locked and Loaded!

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0581
Inspiration via Hydroboration

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0582
Oligo(thienylene-vinylene) by Deprotonative Cross-Coupling

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0583
Azole-Fused B,N-Naphthalenes via Hydroboration

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0584
C-Terminal Modification of Fully Unprotected Peptide Hydrazides

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0585
Sterically Congested PAHs Based on a 1,7-Naphthodiyne Platform

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0586
It’s an Alcohol, It’s a Lactide, It’s a Superelectrophile!

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0587
Synthesis of High Electron Affinity Materials Using Aryl C–H Iodination

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0588
Synthesis of A Newly Class of Si-Bridged π-Conjugated Compounds

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Metal-Catalyzed Asymmetric Synthesis and Stereoselective Reactions
z589
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0589
Ruthenium(II)-Catalyzed Asymmetric Transfer Hydrogenation Reaction FREE ACCESS

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0590
Iridium-Catalyzed Reverse Prenylation of Indole and Tryptophan Derivatives

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0591
Palladium-Catalyzed Asymmetric Carboetherification of Dihydrofurans

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0592
Pd-Catalyzed Enantioselective Alkene Aryloxyarylation through Oxopalladation

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0593
Nickel-Catalyzed Asymmetric Propargyl Claisen Rearrangement

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0594
Spiroketals and -aminals by Gold(I)/ Nickel(II) Asymmetric Relay Catalysis

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0595
Scandium-Catalyzed Regio- and Enantioselective Bromoaminocyclization

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0596
Iridium-Catalyzed Asymmetric C–H Alkylation of N-Sulfonylbenzamides

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0597
Catalytic Asymmetric [3+2] Annulation through C–H Activation

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0598
Palladium-Catalyzed Enantioselective Allylic Alkylation of CF₃-Substituted Compounds

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0599
Regio- and Stereoselective Pd-Catalyzed 1,3-Difunctionalization of Alkenyl Nonaflates

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0600
Copper-Catalyzed trans-Hydroboration of Terminal Aryl Alkynes

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0601
Pd-Catalyzed Asymmetric Aminomethylamination of Conjugated Dienes

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0602
Enantioselective CuH-Catalyzed Hydroallylation of Vinylarenes

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0603
Molybdenum Complex Catalyzed Z-Selective Cross-Metathesis FREE ACCESS

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0604
Rhodium-Catalyzed Asymmetric Conjugate Addition of Arylboronic Acids to Enones

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0605
Copper-Catalyzed Aminoboration of Alkylidenecyclopropanes

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0606
Asymmetric Ir-Catalyzed Spirocyclization and Migration Forming Tetrahydro-β-Carbolines

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0607
Enantioselective Copper(II)-Catalyzed Conjugate Addition

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0608
Palladium-Catalyzed Multicomponent Carbonyl Allylation Reaction

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0609
Iridium-Catalyzed Reductive Amination of Arylacetones

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0610
Asymmetric Chromium-Catalyzed Dearomative 1,2-Addition

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0611
Palladium-Catalyzed Three-Component Reaction for the Allylation of Aldehydes

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0612
Cu-Catalyzed Asymmetric Synthesis of 3,4-Dihydro-2H-1,4-benzoxazines

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0613
Asymmetric Copper-Catalyzed 1,4-Addition to β-Substituted Enones

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0614
Asymmetric Indole Cyclization toward (–)-Aspidophylline A

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0615
Rhodium-Catalyzed Stereoselective Synthesis of Isoindolines

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Metal-Mediated Synthesis
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0617
Suzuki Coupling of Heteroaryl Fluorosulfates

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0618
Synthesis of Trimethylstannanes

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0619
Enantioselective Arylation of Pyridine FREE ACCESS

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0620
One-Pot, Modular Approach to Functionalized Ketones

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0621
Spirocyclization via Hydroarylation of N–Ac Indoles

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0622
Catalytic Asymmetric Addition of Organolithium Reagents

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0623
Copper-Catalyzed 1,2-Additon of Dialkylzinc Reagents

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0624
Diastereoselective Allylzincation of Nonracemic Imines

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0625
Annulation/Arylthiolation Cascade with Arylboronic Acids

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0626
Carbochlorination of Arylacetylene

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0627
Copper-Catalyzed Aminoalkylations

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0628
Suzuki–Miyaura Cross-Coupling Reactions of Aminopyrazoles

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0629
Difluoroalkylation of Arylborons

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0630
One-Pot Synthesis of Arylketones from Aromatic Acids

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0631
Synthesis of Azoles Sulfides via Copper-Catalyzed Cross-Coupling

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Organo- and Biocatalysis
z633
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0633
Direct Mannich-Type Reaction Using a Chiral Organosuperbase Catalyst

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0634
Organocatalytic Kinetic Resolution of Sulfoximines with Enals

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0635
Enzymatic Nitrene Transfer/Sigmatropic Rearrangement to Access Allylic Amines FREE ACCESS

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0636
Asymmetric Ugi Reaction Catalyzed by a Chiral Phosphoric Acid

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0637
Data Set Design for the Asymmetric Fluorination of Allylic Alcohols

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0638
Biomimetic Photoorganocatalytic Chlorination of Arenes

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0639
Enantioselective Synthesis of Silacyclopentanes

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0640
NHC-Catalyzed Enantioselective Enamide−Aldehyde Cross-Coupling

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Polymer-Supported Synthesis
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0641
Doped Carbon Shell Catalysts for Oxidation of Alkanes

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0642
Heterogeneous Photocatalyst for C–H Alkylation of Aliphatic Nitriles

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0643
Sequential C–C Bond Formation via Allylic and Benzylic Boronic Acids FREE ACCESS

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0644
Phosphonylation of Aryl Halides with a Palladium Complex on Fe(III) Oxide in Water

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0645
Chemoselective Reduction of Nitroarenes on Platinum Nanoparticles

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0646
Reusable Polyacid Catalyst for Oxidation of Sulfides and Allylic Alcohols

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0647
Iron(III) Oxide Nanoparticle-Catalyzed Hydrogenation of Nitro Compounds

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0648
Bisoxazoline–Palladium Composite-Catalyzed Suzuki–Miyaura Coupling

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0649
A Gold-NP-Supported Organocatalyst for Asymmetric Aldol Reactions

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0650
Copper(0)/Magnetite-Catalyzed Cyclization of Terminal Alkynes with Isocyanides

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0651
Stabilized Ruthenium Nanoparticles for Oxidation and Hydrogenation Reactions

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0652
Cobalt/Titania-Catalyzed Aerobic Oxidation of Alcohols and Alkanes

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0653
Multistep Continuous-Flow Synthesis of Nitrogen-Containing Compounds

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0654
Au–Cu Alloy Nanoparticles for Photocatalytic Reduction of Nitrobenzenes

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0655
Synthesis of Chromene Derivatives Using PS-Supported PTSA

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0656
Hydrogenation of Halonitrobenzene by Using a Platinum–Zinc Bimetallic Catalyst

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