DOI: 10.1055/s-00000131

Synfacts

Issue 12 · Volume 10 · December 2014 DOI: 10.1055/s-004-28085

Synform

A156
Zanda, Matteo: SYNFORM ISSUE 2014/12

Synthesis of Natural Products and Potential Drugs

z1233
All PDFs of this category
1233
Synthesis of Norleucosceptroids A, B, and K
1234
Collective Synthesis of Humulanolides Using a Metathesis Cascade
1235
Synthesis of Nominal Cycloinumakiol and Structural Revision
1236
Synthesis of Trifluorinated Thiazolines That Target Prohibitins
1237
Synthesis of a c-Kit Kinase Inhibitor Using Organocatalysis
1238
Total Synthesis of (±)-Tubastrindole B
1239
Synthesis of BMS-663068
1240
Synthesis of Nominal Trichodermatide A
1241
Synthesis of Lycopodium Alkaloids Containing Seven-Membered Rings
1242
Synthesis of an Androgen Receptor Modulator
1243
Divergent Total Synthesis of Aspidosperma Alkaloids

Synthesis of Heterocycles

z1245
All PDFs of this category
1246
Synthesis of Imidazo-Fuzed Heterocycles via Gold-Catalyzed Cycloaddition
1247
Inverse-Electron-Demand Diels–Alder Reaction of Asymmetric 1,2,3-Triazines
1248
Pyridazines via an Organophosphorus-Catalyzed Diaza-Wittig Reaction
1249
Palladium-Catalyzed Synthesis of Quinolines From Cyclopropanols
1250
Catalyst-free Synthesis of 1-Aryltetrazoles
1251
Synthesis of Phenanthridines from Diaryliodonium Salts and Nitriles
1252
Synthesis of Oxazinoindoles and Pyrrolooxazines by Sc(III) Catalysis
1253
Amidation–Oxidative Cyclization Route to 2-Aryl-2H-benzotriazoles
1254
Fused Isoquinolones by Aryne/Alkyne Insertion into C–H/N–H Bonds
1255
ArI-Catalyzed Synthesis of Benzolactones
1256
Copper-Catalyzed Synthesis of 1-Bromoindolizines from Pyridines
1257
Enantioselective Synthesis of Pyrrolidinones and Dihydropyridinones
1258
A Photocatalytic Hydroamination Route to Dihydropyrazoles
1259
Synthesis of 1,4-Thiazepin-5(4H)-ones without Transition Metals

Synthesis of Materials and Unnatural Products

z1261
All PDFs of this category
1261
Pass the P2
1262
New Macrocycles on the Scene: O6-Corona[3]arene[3]tetrazines
1263
Alkynes of Routes to Furans, Pyrroles, and Thiophenes
1264
Fluorescent Indazoloquinazolinones by Intramolecular C−H Amination
1265
Sequential Steps Save the Day
1266
A Panchromatically Electrochromic Small Molecule
1267
Expecting Silicon Valley, Finding Silicon Planar
1268
Efficient Heteroarylation of Aromatic Amines via Dual C–H Activation
1269
Next Time You Need a Fluorene, Try a Triazene
1270
Climbing the Bisindeno-[n]thienoacene Ladder, One Rung/Ring at a Time
1271
Air-Stable and Conductive 13-Fused-Ring Thienoacenes
1272
Kick Your MOFs Up a Notch

Metal-Catalyzed Asymmetric Synthesis and Stereoselective Reactions

z1273
All PDFs of this category
1273
Fe(III)-Catalyzed Enantioselective Conia-ene Reaction
1274
Rhodium-Catalyzed Hydroformylation of Z-Enamides and Z-Enol Esters
1275
Iridium-Catalyzed Allylic Substitution of Silyl Dienolates
1276
Nickel-Catalyzed Asymmetric Hydrogenation of Olefins
1277
Asymmetric 1,4-Addition of Alkyl Groups to N-Sulfonyl Imines
1278
Iron(II)-Catalyzed Intermolecular Amino-Oxygenation of Olefins
1279
Copper-Catalyzed Enantioselective Allylic Alkylation Using Terminal Alkynes
1280
Enantioselective Gold-Catalyzed Cyclopropanation of 1,6-Enynes
1281
Enantioselective Trifluoromethylation of Unactivated Alkenes
1282
Chiral Chromanes via Gold-Mediated Cyclization Employing Free Allylic Alcohols
1283
Copper-Mediated E-Selective Trifluoromethylation of α,β-Unsaturated Hydrazones
1284
Iron-Catalyzed Asymmetric Intramolecular Cyclopropanation
1285
Asymmetric Alkene Carboamination by Palladium Catalysis
1286
Asymmetric Synthesis of α,α-Difluoro-β-lactams
1287
Copper-Mediated Enantioselective Hydrobromination of Styrenes
1288
Synthesis of Chiral Pyrazolines via Chiral π-Cation Catalysis
1289
Enantioselective Amination of Racemic Allylic Alcohols
1290
Reverse Regioselective [4+3] Cycloaddition
1291
Iridium-Catalyzed Enantioselective Hydrogenation of Pyridinium Salts
1292
Palladium-Mediated Asymmetric 1,4-Addition of Diarylphosphines to N-Enoyl Phthalimides
1293
Palladium-Mediated Asymmetric Decarboxylative Allylic Alkylations of α-Imino Anions
1294
De Novo Synthesis of P-Stereogenic Compounds via Iridium Catalysis
1295
Enantioselective Hydroalkoxylation of Allene Catalyzed by Palladium
1296
Asymmetric Allylic Alkylation of Hydroxyacrylates Catalyzed by Palladium
1297
Intramolecular Alkene Hydrosilylation Catalyzed by Rhodium
1298
Asymmetric Alkynylation–Lactamization Cascade Catalyzed by Copper
1299
Enantioselective Palladium and Phosphoric Acid Catalyzed Allylations of Aldehydes
1300
Asymmetric Synthesis of Planar Chiral Ferrocenes
1301
Asymmetric Allylic Alkylation of Azlactones with Allylic Alcohols

Metal-Mediated Synthesis

z1303
All PDFs of this category
1303
Catalytic gem-Difluoropropargylation Using Aryl and Alkenyl Boron Reagents
1304
Palladium-Catalyzed Cross-Coupling of Secondary Alkylzinc Reagents
1305
Copper-Mediated Bis-anilide Cyclization by Double C–H/Ar–H Coupling
1306
Enantioselective Protoboration of Disubstituted Allenes
1307
Gold-Catalyzed Cycloisomerization to C2- and C3-Borylated Furans
1308
Toward the O-Arylation of β-Hydroxy-α-Amino Acid Substrates
1309
Cross-Coupling of Organolithium Reagents with Aryl and Vinyl Triflates
1310
Copper-Mediated Acetoxylation
1311
Nickel-Catalyzed Double Carboxylation
1312
Scandium-Catalyzed [3+2] Cycloaddition of Allylsilanes to β-Silylenones
1313
Copper-Catalyzed Silylation of Aldehydes
1314
Three-Component Differential Vicinal Diarylation of Terminal 1,3-Dienes
1315
Cross-Coupling of Unactivated Aryl Sulfides with Arylzinc Reagents
1316
Reaction of Arylboronic Acids with α-Aminoesters and α-Aminoacetonitriles
1317
Noncryogenic Boronate Rearrangement

Organo- and Biocatalysis

z1319
All PDFs of this category
1319
Cascade [4+2] Annulation by NHC Catalysis
1320
Phosphepine-Catalyzed Enantioselective Synthesis of Cyclopentenes
1321
Novel Oligomeric Helical Chiral Catalysts for Asymmetric Dearomatization
1322
Enantioselective Phase-Transfer Alkylation of Sulfenate Anions to Sulfoxides
1323
Organocatalytic Biomimetic Synthesis of Izidine Alkaloids
1324
Synthesis of Dicarbonyls by Combining Organocatalysis and Photoredox Catalysis
1325
Organocatalytic Radical Addition to Alkenes
1326
Brønsted Acid Catalyzed Enantioselective Formation of Tetrahydroxanthenes
1327
Thiourea-Catalyzed Enantioselective Addition of Indoles to Pyrones
1328
Asymmetric Countercation-Directed Nucleophilic Aromatic Substitutions
1329
Enantioselective α-Amination by a BINAM-Derived Phase-Transfer Catalyst
1330
Anion-Binding Catalysis Mediated by Pyridinium Cations

Polymer-Supported Synthesis

z1331
All PDFs of this category
1331
Dendritic Copper Catalysts for Homogeneous Click Chemistry in Water
1332
Ritter Reaction of Alcohols with Nitriles Using NaHSO4/SiO2
1333
Benzylic Oxidation with a Manganese Triazolate Framework
1334
Reductive Amination of Nitriles to Tertiary Amines Using Platinum Nanowire
1335
Reduction of Nitroarenes with NaBH4 Using Graphene-Supported PdCu Nanoparticles
1336
[2+2+2] Cycloaddition Using a Silica-Supported Rh–NHC Catalyst
1337
Aerobic Oxidation and Reduction Using Pd0-in-UiO-67
1338
C3N4-Catalyzed Oxidative Allylation of Tetrahydroisoquinoline Derivatives
1339
The Sonogashira Coupling Using Pdnp-nSTDP
1340
The Sonogashira Coupling with a PS-Supported Palladium Catalyst
1341
Direct C–H Amination of Benzothiazoles Using CuFe2O4 Nanoparticles
1342
Light-Mediated Deiodination and Cyclization Using PtNPs@TiO2
1343
Henry and Suzuki–Miyaura Reactions with SBA-15/CCMet and Pd Complex
1344
Transfer Hydrogenation of Alkenes Using Ni/Ru/Pt/Au Nanoparticles
1345
Titanosilicate Zeolite Catalyzed Selective Oxidation of Sulfides with H2O2

Erratum

1347
Maji, B.; Baidya, M.; Yamamoto, H.: Direct Amination of β-Keto Esters Employing Nitrosocarbonyl ­Compounds
1347
Kim, J. H.; Bouffard, J.; Lee, S.-G.: Tandem Divergent Catalysis using Nitriles
1348
Souillart, L.; Cramer, N.: Enantioselective Carbonyl Carboacylation Initiated by C–C Bond Activation