DOI: 10.1055/s-00000131

Synfacts

Issue 07 · Volume 9 · July 2013 DOI: 10.1055/s-003-25200

Synform

A80
Zanda, Matteo: SYNFORM ISSUE 2013/07

Synthesis of Natural Products and Potential Drugs

z687
All PDFs of this category
0687
Total Synthesis of Linoxepin
0688
Synthesis and Structural Confirmation of Phellodonin and Sarcodonin ε
0689
Synthesis of the Glucocorticoid Agonist BI 653048 BS H3PO4
0690
Synthesis of an Inhibitor of Human Arginases I and II
0691
Formal Synthesis of Oseltamivir Phosphate
0692
Synthesis of (–)-Englerin A
0693
Total Synthesis Echinopine A and B
0694
Synthesis of the GSK3β Inhibitor AZD8926
0695
Total Synthesis of Amphidinolide F
0696
Synthesis of a VLA-4 Antagonist via Electrochemical C–H Amination
0697
Synthesis of Ataciguat via Sulfoximine-Directed Sulfamidation
0698
Synthesis of URB597
0699
Total Synthesis of (–)-Vincorine
0700
Synthesis of l-Carbidopa via Enantioselective α-Amination
0701
Total Synthesis of the Epoxyisoprostanes PECPC and PEIPC
0702
Synthesis of Oxadiazole-Based S1P1 Receptor Agonists
0703
Synthesis of DPC 083

Synthesis of Heterocycles

z705
All PDFs of this category
0705
Aryne-Mediated Route to Substituted Carbazoles
0706
Oxidative Heteroannulation Route to Imidazo[1,5-a]pyridines
0707
Cu-Catalyzed Double C–H Activation–Cyclization Route to Hydrazones
0708
Stereodivergent Oxetan-3-one Syntheses from Allenes
0709
Synthesis of Tricyclic Indoles by an Intramolecular Larock Indole Synthesis
0710
Copper-Mediated Synthesis of Pyrrolo[2,1-f][1,2,4]triazin-4(3H)-ones
0711
Synthesis of Chiral Pyrrolidines via Intra-molecular Thiourea-Catalyzed Cyclization
0712
Heteroannulation Route to 2-Acylindoles and 2-Acylindolines
0713
Benzofuran Synthesis Using a Sonogashira–Larock Heteroannulation Protocol
0714
Phenazine Synthesis Involving Smiles Rearrangement of Intermediate Arynes
0715
Synthesis of Pyrroloindolines via Rh(II)-Catalyzed Annulation of Indoles
0716
Silver(I)-Catalyzed Cycloaddition Route to Pyrroles
0717
Cu-Catalyzed Heteroannulation Route to 2-Substituted Benzo[d]thiazoles
0718
CuBr-Catalyzed C–N Coupling Heteroannulation Route to 3-Aminoindazoles

Synthesis of Materials and Unnatural Products

z719
All PDFs of this category
0719
A Photoelimination Route to Azaborines
0720
Highly Substituted Quinolines in One Step
0721
Expanded Helical Porphyrins
0722
A Simple Methodology Yielding Nitriles from Alcohols
0723
Electrophilic Aromatic Substitutions of Aryltrifluoroborates
0724
Decarbonylation of Diynones Yielding Conjugated Diynes
0725
Synthesis of Depolymerizable Poly(phthalaldehydes) with Responsive End Caps
0726
An Efficient Synthesis of a Tetracyanofulvene Leads Way to New Chromophores
0727
Synthesis of π-Conjugated Molecules Derived from Diimidonaphthalenes
0728
Synthesis of All-Homocalixarenes
0729
An Insertion for Alkynes
0730
Regioselective Access to Dithiononaphthalenes
0731
A Robust, Well-Defined Catalyst for ROAMP: Promoted by Protons and Stable to Air

Metal-Catalyzed Asymmetric Synthesis and Stereoselective Reactions

z733
All PDFs of this category
0733
Pd-Catalyzed Enantioselective Allylic Alkylation of Indoles
0734
Ag(I)-Catalyzed Synthesis of Chiral C(3)-Functionalized Phthalides
0735
Asymmetric Redox-Relay Oxidative Heck Arylations
0736
Rhodium-Catalyzed Asymmetric β-Boration
0737
Cr/Salen-Catalyzed Nazarov Cyclization of Dienones
0738
Gold-Catalyzed Cyclization of Allenols
0739
Nickel-Catalyzed [3+2] Cycloaddition
0740
Asymmetric Ni-Catalyzed Friedel–Crafts Alkylation Reaction
0741
Chiral Mg/Phosphate Complex Catalyzed Diels–Alder Reaction
0742
Cobalt-Catalyzed Kinetic Resolution of Terminal Bis-Epoxides
0743
Chiral Tetrahydrofurans via [3+2] Cycloaddition Catalyzed by Palladium
0744
Cu-Catalyzed γ-Selective Allylic Silylation
0745
Indium/TFA-Catalyzed Cycloannulation
0746
Ruthenium-Catalyzed Asymmetric Transfer Hydrogenation
0747
Sequential Rh- and Pd-Catalyzed C–H Functionalization
0748
Platinum-Catalyzed Enantiospecific Cycloisomerization
0749
Chiral Allenes by Pd-Catalyzed β-Hydride Elimination of Enol Triflates
0750
Asymmetric Au-Catalyzed Oxidative Cyclization of Homopropargyl Amides
0751
Aziridine-Ring Ligands in Asymmetric Synthesis
0752
Pd-Catalyzed Decarboxylative Allylation of Carbazolones and Indolones
0753
Mg(II)-Catalyzed 1,2- and 1,4-Addition of Phosphorus Nucleophiles
0754
Pd-Catalyzed Cycloaddition of tert-Butane-sulfinimines with Trimethylenemethane
0755
Ru-Catalyzed Lactone Synthesis by Hydroacylation of Keto Alcohols
0756
Asymmetric Rh-Catalyzed Intramolecular 1,4-Addition
0757
Regioselective and Enantioselective Cu-Catalyzed Aminoboration of Styrenes
0758
Ir-Catalyzed Enantioselective Desymmetrization of meso-Cyclic Anhydrides
0759
Borane-Catalyzed Asymmetric Imine Hydrogenation
0760
Ruthenium-Catalyzed Asymmetric Allylic Amidation and Radical Cyclization
0761
Asymmetric Cu-Catalyzed Vinylogous Mukaiyama–Michael Addition

Metal-Mediated Synthesis

z763
All PDFs of this category
0763
Highly Diastereoselective Synthesis of α-Amino Amides
0764
Co-Catalyzed C–N Bond Formation with Arylzinc Reagents and N-Chloroamines
0765
Stereoselective Synthesis of All-Carbon Tetrasubstituted Alkenes
0766
Ag-Catalyzed Propargylation and Allylation Reactions of Ketones
0767
Cu-Mediated Cross-Coupling of Benzoic Acid Derivatives and 1,3-Azoles
0768
Suzuki–Miyaura Coupling of Dioxolanylethyltrifluoroborates
0769
Highly Diastereo- and Enantioselective Allylboration of Aldehydes
0770
Direct Functionalization of THF and 1,4-Dioxane via Oxidative C(sp3)–H Arylation
0771
Iron-Catalyzed Arylation of 2,2-Disubstituted Propionamides
0772
Cu-Catalyzed Conjugate Addition of Alkenyl Alanates to Cyclic Enones
0773
Enantiodivergent Hydroboration–Crotylboration Reaction of Allenylsilanes
0774
Cu-Mediated Transformation of Organosilanes to Nitriles
0775
Pd-Catalyzed ortho-Selective C–H Borylation of 2-Phenylpyridine Derivatives
0776
Oxidative para-Triflation of Acetanilides

Organo- and Biocatalysis

z777
All PDFs of this category
0777
Asymmetric Intramolecular Carbosulfenylation of Olefins
0778
Asymmetric Aldol Addition to give 3-Hydroxy Oxindoles
0779
Asymmetric Synthesis of Z-Homoallylic Alcohols by Kinetic Resolution
0780
Asymmetric NHC-Catalyzed Aza-Benzoin Reaction of Enals
0781
Enantioselective Synthesis of Pactamycin by Organocatalysis
0782
Diarylprolinol Silyl Ether Catalyzed Asymmetric Mannich Reaction
0783
Asymmetric Organocatalysis Meets Fullerenes
0784
Direct Asymmetric Vinylogous Aldol Reaction of Allyl Ketones with Isatins
0785
Asymmetric Epoxidation of α,β-Unsaturated Carbonyl Compounds
0786
Synthesis of Chiral Indolines by Catalytic Asymmetric Fischer Indolization
0787
Inverse-Electron-Demand Hetero-Diels–Alder Reaction Using Modular Catalysts
0788
Chiral Lewis Base Catalyzed Asymmetric Synthesis of Diazo Compounds
0789
Asymmetric Conjugate Addition of MeNO2 to β,β-Disubstituted Enones
0790
Aminals as Imine Precursors

Polymer-Supported Synthesis

z791
All PDFs of this category
0791
Alkylation with Primary Alcohols Using NHC-Ir/SBA-15 Catalyst
0792
Preparation of 2,3-Unsubstituted Indoles with MCM-41-SO3H
0793
Suzuki–Miyaura Coupling with Main-Chain Organometallic Polymer
0794
Synthesis of 1-Amidoalkyl-2-Naphthols with S8-NPs
0795
Gold Nanoparticles Catalyzed Dehydrogenative Oxidation of Amines
0796
Asymmetric Henry–Michael Reaction with an Organic–Inorganic Catalyst
0797
Asymmetric Cyclopropanation with Au Nanocluster Catalysts
0798
Synthesis of Indolizines and Chalcones Using CuNPs/C
0799
Suzuki–Miyaura Coupling with CeO2
0800
Suzuki–Miyaura Coupling Using PVC-Supported Pd Nanoparticles
0801
Hydrogenation of Unsaturated C–C Bonds with Iron(0) Nanoparticles
0802
Pd/C-Catalyzed Formic Acid Reduction of Cinchona Alkaloids
0803
Cinchonidium Polymer Catalyzed Asymmetric Alkylation of Glycine Imine Ester

Erratum

0804
King, S. M.; Calandra, N. A.; Herzon, S. B.: Total Synthesis of (–)-Acutumine and (–)-Dechloroacutumine