Palladium-Catalyzed Cross-Coupling Alkylation of Arenediazonium o-Benzenedisulfonimides

Margherita Barbero; Silvano Cadamuro; Stefano Dughera

doi:10.1055/s-2008-1032027

PAPER

Palladium-Catalyzed Cross-Coupling Alkylation of Arenediazonium o-Benzenedisulfonimides

Margherita Barbero, Silvano Cadamuro, Stefano Dughera*
Dipartimento di Chimica Generale ed Organica Applicata, Università di Torino, Corso Massimo d’Azeglio 48, 10125 Torino, Italy
Fax: +39(011)6707642; e-Mail: stefano.dughera@unito.it;

Abstract

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Abstract

Arenediazonium o-benzenedisulfonimides were reacted with tetramethyltin, tetrabutyltin or trialkylboranes. The reactions, carried out in the presence of palladium(II) derivatives as precatalysts, gave the methylation and alkylation products with good overall conversions. The o-benzenedisulfonimide was recovered in high yield from all the reactions and could be recycled for the preparation of other salts.

Key words

palladium - Stille reaction - Suzuki reaction - cross-coupling - diazo compounds

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References

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