Synthesis of Novel α-Aminophosphonates Containing Small Rings

Nikolai V. Yashin; Elena V. Villemson; Andrey V. Chemagin; Elena B. Averina; Maria M. Kabachnik; Tamara S. Kuznetsova

doi:10.1055/s-2008-1032019

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Synthesis 2008(3): 464-468
DOI: 10.1055/s-2008-1032019

PAPER

Synthesis of Novel α-Aminophosphonates Containing Small Rings

Nikolai V. Yashin^a,b, Elena V. Villemson^a, Andrey V. Chemagin^a, Elena B. Averina^a, Maria M. Kabachnik^a, Tamara S. Kuznetsova*^a,b
^a Department of Chemistry, Lomonosov Moscow State University, Leninskie Gory 1-3, Moscow 119992, Russian Federation
Fax: +7(495)9390290; e-Mail: kuzn@org.chem.msu.ru;
^b IPhaC RAS, Severnyi Proezd 1, Chernogolovka, Moscow Region 142432, Russian Federation

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Publication History

Received 24 September 2007
Publication Date:
10 January 2008 (online)

Abstract
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Abstract

The synthesis of cyclopropyl- and cyclobutyl-substituted α-aminophosphonates by three-component microwave-assisted reaction of cyclopropanecarbaldehydes, benzylamine, and diethyl phosphite in the presence of cadmium iodide as catalyst has been developed.

Key words

cyclopropane amino acids - multicomponent reactions - aminophosphorylation - amino(cyclopropyl)methylphosphonates

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