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Synthesis 2007(22): 3447-3450
DOI: 10.1055/s-2007-990876
DOI: 10.1055/s-2007-990876
SHORTPAPER
© Georg Thieme Verlag Stuttgart · New YorkSamarium(III) Triflate Catalyzed Conjugate Addition of Amines to Electron-Deficient Alkenes [1]
Weitere Informationen
Received
5 December 2006
Publikationsdatum:
31. Oktober 2007 (online)
Publikationsverlauf
Publikationsdatum:
31. Oktober 2007 (online)

Abstract
Amines undergo smooth nucleophilic addition to α,β-unsaturated compounds in the presence of a catalytic amount of samarium(III) triflate at ambient temperature to produce the corresponding β-amino compounds in excellent yields. This method is simple, convenient, and works efficiently under mild conditions.
Key words
amines - α,β-unsaturated compounds - conjugate addition - β-amino derivatives
IICT Communication No. 060901.
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References and Notes
IICT Communication No. 060901.