PEG-Supported Dipyridyl Ligand for Palladium-Catalyzed Suzuki and Suzuki-Type Reactions in PEG and Aqueous Media

Wenpeng Mai; Lianxun Gao

doi:10.1055/s-2006-951488

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Synlett 2006(16): 2553-2558
DOI: 10.1055/s-2006-951488

LETTER

PEG-Supported Dipyridyl Ligand for Palladium-Catalyzed Suzuki and Suzuki-Type Reactions in PEG and Aqueous Media

Wenpeng Mai, Lianxun Gao*
State Key Laboratory of Polymer Physics and Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Graduate School of Chinese Academy of Sciences, Changchun 130022, P. R. of China
Fax: +86(431)5685653; e-Mail: lxgao@ciac.jl.cn;

Further Information

Publication History

Received 27 June 2006
Publication Date:
22 September 2006 (online)

Abstract
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Abstract

An air- and water-stable PEG-supported bidentate nitrogen ligand is prepared and its applications in the palladium-catalyzed Suzuki reaction of aryl halides with arylboronic acids in PEG and Suzuki-type reaction of aryl halides with sodium tetraphenylborate in aqueous media are reported. The homogeneous catalyst system is environmentally friendly and offers the advantages of high activity, reusability and easy separation.

Key words

Suzuki reaction - ligand - reusability - PEG

References

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