Abstract
The palladium-catalyzed hydroxycarbonylation of aryl and vinyl bromides in the presence
of acetic anhydride and lithium formate as a carbon monoxide source has been developed.
The combination of palladium(II) acetate with 1,1′-bis(diphenylphosphino)ferrocene
(dppf) is an efficient catalytic system when the reaction is carried out at 120 °C.
Key words
hydroxycarbonylation - palladium - catalysis - aryl bromides - carboxylic acids
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