Synthesis 2006(18): 3063-3066  
DOI: 10.1055/s-2006-942541
PAPER
© Georg Thieme Verlag Stuttgart · New York

A Novel Method for the Synthesis of Bis(1-diethoxyphosphorylalkyl)amines from Diimines

Babak Kaboudin*, Ehsan Jafari
Department of Chemistry, Institute for Advanced Studies in Basic Sciences (IASBS), Gava Zang, Zanjan 45195-1159, Iran
Fax: +98(241)4249023; e-Mail: kaboudin@iasbs.ac.ir;
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Publikationsverlauf

Received 31 May 2006
Publikationsdatum:
02. August 2006 (online)

Abstract

A novel and convenient method for the synthesis of bis(1-diethoxyphosphorylalkyl) amines has been developed. As described below, treatment of aromatic diimines with diethyl phosphite in the presence of chlorotrimethylsilane gave bis(1-diethoxyphosphorylalkyl)amines. This method is easy, rapid, and good-yielding for the synthesis of bis(1-diethoxyphosphoryl­alkyl)amines from simple starting materials.