Abstract
In this paper we describe the synthesis of β,δ-diketoester substituted 1,7,9-undecatrienes
and their intramolecular Diels-Alder (IMDA) cycloadditions under thermal and acid-catalysed
conditions. Application of this chemistry in the synthesis of a solanapyrone D precursor
is reported.
Key words
intramolecular Diels-Alder reaction - polyketide - solanapyrone D
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