Synthesis of Anthryl Sulfides from Anthryl Methyl Ethers via Acid-Catalyzed Ether-Sulfide Exchange Reaction

Krishnan Radhakrishnan; Chih-Hsiu Lin

doi:10.1055/s-2005-872268

LETTER

Synthesis of Anthryl Sulfides from Anthryl Methyl Ethers via Acid-Catalyzed Ether-Sulfide Exchange Reaction

Krishnan Radhakrishnan, Chih-Hsiu Lin*
Institute of Chemistry, Academia Sinica, Taipei 115, Taiwan
Fax: +886(2)27831237; e-Mail: chl@chem.sinica.edu.tw;

Abstract

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Abstract

Under acidic condition, anthryl methyl ethers behave as anthryl cation synthons and undergo ipso-substitution to produce anthryl sulfides. These compounds are hard to access with currently available methodology and they have great potentials as organic electronic materials.

Key words

arene - nucleophilic aromatic substitution - heterocycles - macrocycles - sulfur

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References

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