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Synlett 2005(11): 1787-1788  
DOI: 10.1055/s-2005-871542
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© Georg Thieme Verlag Stuttgart · New York

Nickel-Catalyzed Cross-Coupling Reaction of Aryl Halides with Allylic Zirconium Reagents Generated in situ from Zirconocene(alkene) Complexes

Koji Hirano, Kazuya Fujita, Hideki Yorimitsu, Koichiro Oshima*
Department of Material Chemistry, Graduate School of Engineering, Kyoto University, Kyoto-daigaku Katsura, Nishikyo-ku, Kyoto 615-8510, Japan
e-Mail: oshima@orgrxn.mbox.media.kyoto-u.ac.jp;
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Publication History

Received 1 April 2005
Publication Date:
14 June 2005 (online)

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Abstract

Allylic zirconium reagents that are generated in situ via allylic C-H bond activation of alkenes proved to serve as metal counterparts in nickel-catalyzed cross-coupling reactions.

Key words

zirconium - cross-coupling - nickel - C-H bond activation - allylic metal

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