Synthesis 2005(8): 1245-1250  
DOI: 10.1055/s-2005-861859
PAPER
© Georg Thieme Verlag Stuttgart · New York

Synthesis and Epoxidation of 1,3-, 1,4-, and 1,5-Alkadienes with Pentafluoro-λ6-sulfanyl (SF5) Groups

Valery K. Brel*
Institute of Physiologically Active Compounds of Russian Academy of Science, Chernogolovka, Moscow region, 142432, Russia
Fax: +7(095)7857024; e-Mail: brel@ipac.ac.ru;
Further Information

Publication History

Received 29 November 2004
Publication Date:
23 March 2005 (online)

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Abstract

This paper describes a convenient and efficient synthesis of new pentafluoro-λ6-sulfanyl-containing 1,3-, 1,4- and 1,5-alkadienes and their epoxidation. These compounds are useful as monomers or as intermediates in the preparation of polymers, polymer surface coating and SF5-containing heterocyclic compounds.