Electrochemical Oxidation of Benzoins to Benzils in the Presence of a Catalytic Amount of KI in Basic Media

Abstract

Various benzoins were transformed into the corresponding benzils via an electrochemical method. Although the strategy of oxidizing benzoins to the corresponding benzils is generally chosen depending on the nature of the aromatic moiety, the electrochemical technique reported herein allows oxidation that is widely applicable, and without the use of environmentally undesirable oxidants.

alcohols - ketones - dehydrogenations - iodine - electron transfer

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