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Synlett 2004(10): 1820-1822
DOI: 10.1055/s-2004-829570
DOI: 10.1055/s-2004-829570
LETTER
© Georg Thieme Verlag Stuttgart · New York
Facile, Efficient and Chemoselective Palladium(0)-Catalyzed Isomerization of 2-Vinylidenehydrofurans into Valuable Functionalized 1,3-Dienes
Further Information
Received
9 April 2004
Publication Date:
15 July 2004 (online)
Publication History
Publication Date:
15 July 2004 (online)
Abstract
Highly sensitive functionalized 2-vinylidene-hydrofurans undergo a facile, clean and chemoselective Pd(0)-catalyzed isomerization leading to stable and valuable 3-oxa-1,3-dienes precursor of polycyclic systems found in bioactive natural products through Diels-Alder reaction.
Key words
2-vinylidenehydrofurans - Pd(0)-catalyzed isomerization - 3-oxa-1,3-dienes - Diels-Alder
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