Fluorosulfur Containing Pincer Potential Ligands, 1,3-(CH2SRf)2C6H4 and 1,2,4,5-(CH2SRf)4C6H2. X-Ray Structure of...

Maribel Arroyo; Ruy Cervantes; Valente Gómez-Benítez; Paola López; David Morales-Morales; Hugo Torrens; Rubén A. Toscano

doi:10.1055/s-2003-40514

PAPER

Fluorosulfur Containing Pincer Potential Ligands, 1,3-(CH₂SR_f)₂C₆H₄ and 1,2,4,5-(CH₂SR_f)₄C₆H₂. X-Ray Structure of 1,3-(CH₂SC₆F₅)₂C₆H₄

Maribel Arroyo*^a, Ruy Cervantes^b, Valente Gómez-Benítez^c, Paola López^a, David Morales-Morales^c, Hugo Torrens^b, Rubén A. Toscano^c
^a Centro de Química del Instituto de Ciencias, BUAP, Apdo. Postal J-42, San Manuel, C. P. 72571, Puebla, Pue., México
Fax: +52(222)2295551; e-Mail: slarroyo@siu.buap.mx;
^b División de Estudios de Posgrado, Facultad de Química, UNAM, Cd. Universitaria, D. F. 04510 México
^c Instituto de Química, UNAM, Cd. Universitaria, D. F. 04510 México

Abstract

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Abstract

The fluorosulfur containing pincer ligands 1,3-(CH₂SR_f)₂C₆H₄ [R_f = C₆F₅ (1) and 4-HC₆F₄ (2)] and 1,2,4,5-(CH₂SR_f)₄C₆H₂ [R_f = C₆F₅ (3) and 4-HC₆F₄ (4)] have been prepared by treatment of 1,3-(CH₂Br)₂C₆H₄ or 1,2,4,5-(CH₂Br)₄C₆H₂ with the corresponding lead thiolate Pb(SR_f)₂.

Key words

fluorine - sulfur - fluorinated pincer ligands

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References

<A NAME="RM00503SS-1A">1a</A> Fluorine in Agriculture Banks RE. Fluorine Technology Limited Sale; Cheshire U. K.: 1995.

<A NAME="RM00503SS-1B">1b</A> Biomedical Frontiers of Fluorine Chemistry, ACS Symposium Series 639 Ojima I. McCarthy JR. Welch JT. American Chemical Society; Washington D.C.: 1996.

<A NAME="RM00503SS-2">2</A> Filler R. Kobayashi Y. Biomedical Aspects of Fluorine Chemistry Elsevier; Amsterdam: 1982.

<A NAME="RM00503SS-3">3</A> Camps F. Coll J. Fabrias G. Guerrero A. Tetrahedron 1984, 40: 2871

<A NAME="RM00503SS-4">4</A> Thenappan A. Burton DJ. J. Org. Chem. 1990, 55: 4639

<A NAME="RM00503SS-5">5</A> McCarthy JR. Jarvi ET. Matthews DP. Edwards ML. Prakash NJ. Bowlin TL. Mehdi S. Sunkara PS. Bey P. J. Am. Chem. Soc. 1989, 111: 1127

<A NAME="RM00503SS-6">6</A> Patrik TB. Nadji S. J. Fluorine Chem. 1990, 49: 147

<A NAME="RM00503SS-7">7</A> de Wolf ACA. van Koten G. Deelman B. Chem. Soc. Rev. 1999, 28: 37

<A NAME="RM00503SS-8">8</A> Davis FA. Kasu PVN. Sundrababu G. Qi H. J. Org. Chem. 1997, 62: 7546

<A NAME="RM00503SS-9">9</A> Enders D. Potthoff M. Raabe G. Runsink J. Angew. Chem., Int. Ed. Engl. 1997, 36: 2362

<A NAME="RM00503SS-10">10</A> Inorganic Fluorine Chemistry Toward the 21st Century, ACS Symposium Series 555 Trasher SJ. Strauss SH. American Chemical Society; Washington D.C.: 1994.

<A NAME="RM00503SS-11A">11a</A> Dijkstra HP. Meijer MD. Patel J. Kreiter R. van Klink GMP. Lutz M. Spek AL. Canty AJ. van Koten G. Organometallics 2001, 20: 3159

<A NAME="RM00503SS-11B">11b</A> Giménez R. Swager TM. J. Mol. Cat. A 2001, 166: 265

<A NAME="RM00503SS-11C">11c</A> Loeb SJ. Shimizu GKH. Wisner JA. Organometallics 1998, 17: 2324

<A NAME="RM00503SS-11D">11d</A> Bergbreiter DE. Osburn PL. Liu Y.-S. J. Am. Chem. Soc. 1999, 121: 9531

<A NAME="RM00503SS-11E">11e</A> van Manen H.-J. Fokkens RH. van Veggel FCJM. Reinhoudt DN. Eur. J. Org. Chem. 2002, 3189

<A NAME="RM00503SS-11F">11f</A> Evans DR. Huang M. Seganish WM. Chege EW. Lam Y.-F. Fettinger JC. Williams TL. Inorg. Chem. 2002, 41: 2633

<A NAME="RM00503SS-11G">11g</A> Albrecht M. van Koten G. Angew. Chem., Int. Ed. 2001, 40: 3750

<A NAME="RM00503SS-12A">12a</A> Arroyo M. Bernès S. Brianzó JL. Mayoral E. Richards RL. Rius J. Torrens H. Inorg. Chem. Commun. 1998, 1: 273

<A NAME="RM00503SS-12B">12b</A> Arroyo M. Bernès S. Brianzó JL. Mayoral E. Richards RL. Rius J. Torrens H. J. Organomet. Chem. 2000, 599: 170

<A NAME="RM00503SS-12C">12c</A> Morales-Morales D. Redón R. Wang Z. Lee DW. Yung C. Magnuson K. Jensen CM. Can. J. Chem. 2001, 79: 823

<A NAME="RM00503SS-12D">12d</A> Morales-Morales D. Redón R. Lee DW. Wang Z. Jensen CM. Organometallics 2001, 20: 1144

<A NAME="RM00503SS-12E">12e</A> Morales-Morales D. Cramer RE. Jensen CM. J. Organomet. Chem. 2002, 654: 44

<A NAME="RM00503SS-12F">12f</A> Gu X. Chen W. Morales-Morales D. Jensen CM. J. Mol. Catal. A 2002, 189: 119

<A NAME="RM00503SS-12G">12g</A> Morales-Morales D. Rodríguez-Morales S. Dilworth JR. Sousa-Pedrares A. Zheng Y. Inorg. Chim. Acta 2002, 332: 101

<A NAME="RM00503SS-13">13</A> Jensen CM. Chem. Commun. 1999, 2443

<A NAME="RM00503SS-14A">14a</A> Morales-Morales D. Grause C. Kasaoka K. Redón R. Cramer RE. Jensen CM. Inorg. Chim. Acta 2000, 300: 958

<A NAME="RM00503SS-14B">14b</A> Morales-Morales D. Redón R. Yung C. Jensen CM. Chem. Commun. 2000, 1619

<A NAME="RM00503SS-15A">15a</A> Hills A. Hughes DL. Richards RL. Arroyo M. Cruz-Garritz D. Torrens H. J. Chem. Soc., Dalton Trans. 1991, 1281

<A NAME="RM00503SS-15B">15b</A> Arroyo M. Chamizo JA. Hughes DL. Richards RL. Román P. Sosa P. Torrens H. J. Chem. Soc., Dalton Trans. 1994, 1819

<A NAME="RM00503SS-15C">15c</A> Moreno-Esparza R. Torrens H. Arroyo M. Briansó JL. Miravitlles C. Rius J. Polyhedron 1995, 14: 1601

<A NAME="RM00503SS-15D">15d</A> Abasq M.-L. Pickett CJ. Richards RL. Arroyo M. Chamizo JA. Calderón A. Sosa P. Torrens H. Polyhedron 1996, 15: 3623

<A NAME="RM00503SS-15E">15e</A> Arroyo M. Bernès S. Meléndez L. Richards RL. Torrens H. Trans. Met. Chem. 2001, 26: 608

<A NAME="RM00503SS-15F">15f</A> Redón R. Torrens H. Wang Z. Morales-Morales D. J. Organomet. Chem. 2002, 654: 16

<A NAME="RM00503SS-15G">15g</A> Redón R. Cramer R. Bernès S. Morales D. Torrens H. Polyhedron 2001, 20: 3119

<A NAME="RM00503SS-15H">15h</A> Morales-Morales D. Zheng Y. Dilworth JR. Redón R. Torrens H. Inorg. Chim. Acta 2001, 314: 37

<A NAME="RM00503SS-15I">15i</A> Torrens H. Coord. Chem. Rev. 2000, 196: 331

<A NAME="RM00503SS-15J">15j</A> Torrens H. Trends Organomet. Chem. 1994, 1: 523

<A NAME="RM00503SS-16">16</A> Gómez-Benítez V. Hernández-Ortega S. Morales-Morales D. Inorg. Chim. Acta 2003, 346: 256

<A NAME="RM00503SS-17A">17a</A> Martin E. Tovilla J. Torrens H. Synthesis 2000, 1109

<A NAME="RM00503SS-17B">17b</A> Eller PJ. Meek DW. J. Organomet. Chem. 1970, 2: 631

<A NAME="RM00503SS-17C">17c</A> Belf LJ. Buxton MW. Fuller G. J. Chem. Soc. 1965, 3372

<A NAME="RM00503SS-17D">17d</A> Johnston LJ. Peach ME. J. Fluorine Chem. 1978, 12: 41

<A NAME="RM00503SS-17E">17e</A> Ward EW. Sicree S. Chen B. Tamborski C. J. Fluorine Chem. 1995, 73: 73

<A NAME="RM00503SS-17F">17f</A> Peach ME. Spinney HG. Can. J. Chem. 1971, 49: 644

<A NAME="RM00503SS-18">18</A> Bertrán A. García J. Martin E. Sosa P. Torrens H. Rev. Soc. Quim. Mex. 1993, 37(4): 185 ; Chem. Abstr. 1993, 122, 329084j

CCDC-204609 contains the supplementary crystallographic data for this paper.

<A NAME="RM00503SS-20">20</A> Peach M. E.; Can. J. Chem.; 1968, 46: 2699

<A NAME="RM00503SS-21">21</A> Sheldrick GM. SHELXL-97, Program for Crystal Refinement University of Göttingen; Germany: 1997.

Fluorosulfur Containing Pincer Potential Ligands, 1,3-(CH2SRf)2C6H4 and 1,2,4,5-(CH2SRf)4C6H2. X-Ray Structure of 1,3-(CH2SC6F5)2C6H4

Fluorosulfur Containing Pincer Potential Ligands, 1,3-(CH₂SR_f)₂C₆H₄ and 1,2,4,5-(CH₂SR_f)₄C₆H₂. X-Ray Structure of 1,3-(CH₂SC₆F₅)₂C₆H₄