Hai X,
Zheng Y,
Yu Q,
Guo N,
Xi S,
*,
Zhao X,
Mitchell S,
Luo X,
Tulus V,
Wang M,
Sheng X,
Ren L,
Long X,
Li J,
He P,
Lin H,
Cui Y,
Peng X,
Shi J,
Wu J,
Zhang C,
Zou R,
Guillén-Gosálbez G,
Pérez-Ramírez J,
*,
Koh MJ,
*,
Zhu Y,
*,
Li J,
*,
Lu J.
*
National University of Singapore and Agency for Science, Technology and Research,
Singapore; ETH Zurich, Switzerland; Tsinghua University, Beijing and Southern University
of Science and Technology, Shenzhen, P. R. of China
Geminal-Atom Catalysis for Cross-Coupling.
Nature 2023;
622: 754-760
DOI:
10.1038/s41586-023-06529-z
Key words
cross-coupling - carbon nitride - heterogeneous catalyst
Significance
A heterogeneous copper catalyst supported on polymeric carbon nitride (Cug/PCN) catalyzed cross-coupling reactions of aryl halides with amines, alcohols, alkynes,
arenes, or thiols, resulting in the formation of the corresponding C–N, C–O, C–C or
C–S coupled products (eqs. 2-5).
Comment
Cug/PCN was prepared according to equation 1. Cug/PCN contains regularly spaced copper atom pairs, with a Cu–Cu distance of approximately
4 Å.
