Dedicated to Late Mr. Balaram Chatterjee
A simple protocol catalyzed by a Brønsted acid, trifluoromethanesulfonic acid (CF3SO3H), to synthesize conjugated diene-diones from easily accessible tertiary propargyl
alcohols and 1,3-dicarbonyl compounds is described. Reactions are performed in an
air atmosphere by using undried solvents with water being the environmentally benign
side product of the process. Preliminary synthetic applications of the conjugated
diene-diones in the formation of conjugated dieneones and furans are also reported
herein.
Key words
Brønsted acid - catalysis - propargyl alcohols - 1,3-dicarbonyl compounds - conjugated
diene-diones