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Synthesis 2023; 55(14): 2228-2240
DOI: 10.1055/s-0041-1738435
DOI: 10.1055/s-0041-1738435
paper
Special Issue Honoring Prof. Guoqiang Lin’s Contributions to Organic Chemistry
Copper(I)-Catalyzed Enantioselective 1,4-Conjugate Hydrophosphination of α,β-Unsaturated Esters
We gratefully acknowledge the financial support from the National Natural Science Foundation of China (No. 22271302), the Science and Technology Commission of Shanghai Municipality (No. 20JC1417100 and No. 21XD1424800), the Key Laboratory of Synthetic Chemistry of Natural Substances, CAS, and Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences.
Abstract
A copper-catalyzed enantioselective 1,4-conjugate hydrophosphination is achieved by employing α,β-unsaturated esters as electrophiles and diarylphosphines as pronucleophiles. An array of chiral phosphines was prepared in high to excellent enantioselectivity. Moreover, a triple catalytic symmetric conjugate hydrophosphination occurred smoothly to afford the product.
Key words
copper(I) catalysis - asymmetric catalysis - conjugate addition - hydrophosphination - α,β-unsaturated estersSupporting Information
- Supporting information for this article is available online at https://doi.org/10.1055/s-0041-1738435.
- Supporting Information
Publication History
Received: 13 February 2023
Accepted after revision: 17 March 2023
Article published online:
17 April 2023
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