Copper(I)-Catalyzed Enantioselective 1,4-Conjugate Hydrophos­phination of α,β-Unsaturated Esters

Ye Wang; Zi-Qing Wang; Liang Yin

doi:10.1055/s-0041-1738435

Synthesis, Inhaltsverzeichnis

Synthesis 2023; 55(14): 2228-2240
DOI: 10.1055/s-0041-1738435

paper

Special Issue Honoring Prof. Guoqiang Lin’s Contributions to Organic Chemistry

Copper(I)-Catalyzed Enantioselective 1,4-Conjugate Hydrophosphination of α,β-Unsaturated Esters

Authors

Ye Wang

^aCollege of Chemistry and Materials Science, Sichuan Normal University, Chengdu, Sichuan 610068, P. R. of China

^bCAS Key Laboratory of Synthetic Chemistry of Natural Substances, Centre for Excellence in Molecular Synthesis, Shanghai Institute of Organic Chemistry, University of Chinese Academy of Sciences, Chinese Academy of Sciences, Shanghai 200032, P. R. of China
Zi-Qing Wang∗

^bCAS Key Laboratory of Synthetic Chemistry of Natural Substances, Centre for Excellence in Molecular Synthesis, Shanghai Institute of Organic Chemistry, University of Chinese Academy of Sciences, Chinese Academy of Sciences, Shanghai 200032, P. R. of China
Liang Yin ∗

^bCAS Key Laboratory of Synthetic Chemistry of Natural Substances, Centre for Excellence in Molecular Synthesis, Shanghai Institute of Organic Chemistry, University of Chinese Academy of Sciences, Chinese Academy of Sciences, Shanghai 200032, P. R. of China

Abstract

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Abstract

A copper-catalyzed enantioselective 1,4-conjugate hydrophosphination is achieved by employing α,β-unsaturated esters as electrophiles and diarylphosphines as pronucleophiles. An array of chiral phosphines was prepared in high to excellent enantioselectivity. Moreover, a triple catalytic symmetric conjugate hydrophosphination occurred smoothly to afford the product.

Key words

copper(I) catalysis - asymmetric catalysis - conjugate addition - hydrophosphination - α,β-unsaturated esters

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Referenzen

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Copper(I)-Catalyzed Enantioselective 1,4-Conjugate Hydrophos­phination of α,β-Unsaturated Esters

Authors

Copper(I)-Catalyzed Enantioselective 1,4-Conjugate Hydrophosphination of α,β-Unsaturated Esters