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Synthesis 2020; 52(20): 3001-3006
DOI: 10.1055/s-0040-1707899
DOI: 10.1055/s-0040-1707899
paper
An Efficient Copper-Catalyzed C(sp2)–S Formation Starting from Aryl Iodides and Tetramethylthiuram Monosulfide (TMTM)
Financial support from Hubei Key Laboratory of Radiation Chemistry and Functional Materials, Hubei University of Science & Technology (2019-20KZ01), Ministry of Education Key Laboratory for the Synthesis and Application of Organic Functional Molecules, Hubei University (KLSAOFM1810), Science and Technology Department of Hubei Province (2019CFB596), Key Laboratory of Hubei Province for Coal Conversion and New Carbon Materials (WKDM202003) are greatly appreciated.Further Information
Publication History
Received: 22 April 2020
Accepted after revision: 01 June 2020
Publication Date:
20 July 2020 (online)
Abstract
A new, efficient copper-catalyzed C(sp2)–S formation of phenyl dithiocarbamates starting from aryl iodides and tetramethylthiuram monosulfide (TMTM) was developed. The target compounds, phenyl dithiocarbamates with active sites, were synthesized smoothly in good to excellent yields. The easy performance, high yields, decent functional group compatibility, and cost-effective substrates make the protocol practical and attractive in C–S bond formation.
Supporting Information
- Supporting information for this article is available online at https://doi.org/10.1055/s-0040-1707899.
- Supporting Information
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