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Synthesis 2020; 52(13): 1969-1980
DOI: 10.1055/s-0039-1690848
DOI: 10.1055/s-0039-1690848
paper
Co(II)-Catalyzed Desilylative Annulation of Benzamides and Acrylamides with Alkynylsilanes: Access to 3-Methyleneisoindolin-1-one and 5-Methylene-1H-pyrrol-2(5H)-one Derivatives
Authors
Funding from Natural Science Foundation of China (No. 51963010 and 21704036) and Science Funds of the Education Office of Jiangxi Province (No. GJJ180601) is acknowledged.
Further Information
Publication History
Received: 02 December 2019
Accepted after revision: 13 February 2020
Publication Date:
03 March 2020 (online)
§ These authors contributed equally.
Abstract
The cobalt-catalyzed desilylative annulation of C(sp2)–H bonds of benzamides and acrylamides with alkynylsilanes assisted by an 8-aminoquinolyl directing group is reported. A variety of benzamides and acrylamides were compatible in this protocol to construct various 3-methyleneisoindolin-1-one and 5-methylene-1H-pyrrol-2(5H)-one derivatives with Z-configuration selectivity in moderate to high yields.
Key words
cobalt catalysis - desilylative annulation - benzamides and acrylamides - alkynylsilanes - 3-methyleneisoindolin-1-one - 5-methylene-1H-pyrrol-2(5H)-oneSupporting Information
- Supporting information for this article is available online at https://doi.org/10.1055/s-0039-1690848.
- Supporting Information (PDF)
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