Combining Amines and 3-(2-Pyridyl)-[1,2,3]Triazolo[1,5-a]pyridine: An Easy Access to New Functional Polynitrogenated Ligands

Leonardo Chiassai; Rafael Ballesteros-Garrido; Maria Paz Clares; Enrique García-España; Rafael Ballesteros; Belén Abarca

doi:10.1055/s-0037-1611901

Synthesis, Table of Contents

Synthesis 2019; 51(21): 4034-4042
DOI: 10.1055/s-0037-1611901

paper

Combining Amines and 3-(2-Pyridyl)-[1,2,3]Triazolo[1,5-a]pyridine: An Easy Access to New Functional Polynitrogenated Ligands

Leonardo Chiassai

^aDepartament de Química Orgànica, Universitat de València, Av. Vicent Andrés Estellés s/n, 46100 Burjassot, Valencia, Spain Email: Rafael.Ballesteros@uv.es Email: Belen.Abarca@uv.es

,

Rafael Ballesteros-Garrido

^aDepartament de Química Orgànica, Universitat de València, Av. Vicent Andrés Estellés s/n, 46100 Burjassot, Valencia, Spain Email: Rafael.Ballesteros@uv.es Email: Belen.Abarca@uv.es

^bI2SysBio, Universitat de València, CSIC, C/Catedrático Agustín Escardino, 9, 46980 Paterna, Valencia, Spain

,

Maria Paz Clares

^cInstituto de Ciencia Molecular (ICMOL), Universitat de València, c/Cat. José Beltrán 2, 46980 Paterna, Valencia, Spain

,

Enrique García-España

^cInstituto de Ciencia Molecular (ICMOL), Universitat de València, c/Cat. José Beltrán 2, 46980 Paterna, Valencia, Spain

,

Rafael Ballesteros∗

^aDepartament de Química Orgànica, Universitat de València, Av. Vicent Andrés Estellés s/n, 46100 Burjassot, Valencia, Spain Email: Rafael.Ballesteros@uv.es Email: Belen.Abarca@uv.es

,

Belén Abarca∗

^aDepartament de Química Orgànica, Universitat de València, Av. Vicent Andrés Estellés s/n, 46100 Burjassot, Valencia, Spain Email: Rafael.Ballesteros@uv.es Email: Belen.Abarca@uv.es

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Abstract

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Abstract

Triazolopyridine-pyridine amine ligands are easily obtained by means of either thermal- or copper(II)-mediated reactions. Starting from a readily accessible iodo derivative of triazolopyridine-pyridine and different amines, this new family of compounds combines aromatic and aliphatic nitrogen atoms with promising coordinating properties. Furthermore, chemical derivatization of a new triazolopyridine-pyridine diamine compound, N1-[6-([1,2,3]triazolo[1,5-a]pyridin-3-yl)pyridin-2-yl]ethan-1,2-diamine, allows the preparation of several remote-pyridine-containing ligands.

Key words

triazolopyridines - nitrogenated ligands - copper catalysis - heterocycles

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References

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