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Synthesis 2019; 51(17): 3320-3326
DOI: 10.1055/s-0037-1611832
DOI: 10.1055/s-0037-1611832
paper
Cobalt-Catalyzed Cycloisomerization of N,N-Diallylanilines
Authors
This work was supported partially from the National Natural Science Foundation of China (No. 21702014 and 21572017) and the Fundamental Research Funds for the Central Universities (XK1802-6).
Further Information
Publication History
Received: 01 March 2019
Accepted after revision: 24 April 2019
Publication Date:
09 May 2019 (online)
Abstract
Cobalt catalysts bearing 2-imino-1,10-phenanthroline ligands are quite efficient bench-stable catalysts for the oligomerization of ethylenes. Herein, their further application was developed in the catalytic transformation of N,N-diallylanilines to pyrrolidines through a cycloisomerization process. In this protocol, chlorobenzene is a vital additive to promote reaction efficiency.
Key words
cycloisomerization - cobalt-catalyzed - pyrrolidine - N,N-diallylaniline - phenanthroline ligandSupporting Information
- Supporting information for this article is available online at https://doi.org/10.1055/s-0037-1611832.
- Supporting Information (PDF) (opens in new window)
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