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Synfacts 2018; 14(12): 1283
DOI: 10.1055/s-0037-1609642
DOI: 10.1055/s-0037-1609642
Metal-Mediated Synthesis
para-Ketonization Using Electrophilic Vinyl Ethers
Maji A,
Dahiya A,
Lu G,
Bhattacharya T,
Brochetta M,
Zanoni G.
*
LiU P.
*
Maiti D.
* Indian Institute of Technology, Mumbai, India; University of Pittsburgh, USA; Università degli Studi di Pavia, Italy
H-Bonded Reusable Template Assisted para-Selective Ketonisation using Soft Electrophilic Vinyl Ethers.
Nat. Commun. 2018;
9: 3582
H-Bonded Reusable Template Assisted para-Selective Ketonisation using Soft Electrophilic Vinyl Ethers.
Nat. Commun. 2018;
9: 3582
Further Information
Publication History
Publication Date:
19 November 2018 (online)
Significance
The authors report a direct para-selective ketonization of arenes. This method makes use of a reusable template to ensure high selectivity.
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Comment
A well-defined hard–soft interaction suppresses competitive routes and enables the functionalization of often challenging electron-poor systems.
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