Nonenzymatic Biomimetic Synthesis of Black Tea Pigment Theaflavins

Abstract

Theaflavins are reddish-orange black tea pigments with a benzotropolone chromophore, and their various biological activities have been reported. Theaflavins are produced by oxidative coupling between catechol-type and pyrogallol-type catechins via bicyclo[3.2.1]octane-type intermediates. In this study, a new method for nonenzymatic biomimetic synthesis of theaflavins was developed using the DPPH radical as an oxidizing agent.

Key words

theaflavins - quinones - black tea - benzotropolones - bicy­clo[3.2.1]octane - biomimetic synthesis

• References and Notes


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