Activation of Small Molecules at N-Heterocyclic Carbene Centers

Hayoung Song; Youngsuk Kim; Junbeom Park; Kimoon Kim; Eunsung Lee

doi:10.1055/s-0035-1560366

Synlett, Inhaltsverzeichnis

Synlett 2016; 27(04): 477-485
DOI: 10.1055/s-0035-1560366

synpacts

Activation of Small Molecules at N-Heterocyclic Carbene Centers

Hayoung Song

^aCenter for Self-Assembly and Complexity, Institute for Basic Science (IBS), Pohang, 790–784, Republic of Korea

^bDepartment of Chemistry, Pohang University of Science and Technology (POSTECH), Pohang, 790–784, Republic of Korea eMail: eslee@postech.ac.kr

,

Youngsuk Kim

^aCenter for Self-Assembly and Complexity, Institute for Basic Science (IBS), Pohang, 790–784, Republic of Korea

^bDepartment of Chemistry, Pohang University of Science and Technology (POSTECH), Pohang, 790–784, Republic of Korea eMail: eslee@postech.ac.kr

,

Junbeom Park

^aCenter for Self-Assembly and Complexity, Institute for Basic Science (IBS), Pohang, 790–784, Republic of Korea

^bDepartment of Chemistry, Pohang University of Science and Technology (POSTECH), Pohang, 790–784, Republic of Korea eMail: eslee@postech.ac.kr

,

Kimoon Kim

^aCenter for Self-Assembly and Complexity, Institute for Basic Science (IBS), Pohang, 790–784, Republic of Korea

^bDepartment of Chemistry, Pohang University of Science and Technology (POSTECH), Pohang, 790–784, Republic of Korea eMail: eslee@postech.ac.kr

^cDivision of Advanced Materials Science, Pohang University of Science and Technology (POSTECH), Pohang, 790–784, Republic of Korea

,

Eunsung Lee*

^aCenter for Self-Assembly and Complexity, Institute for Basic Science (IBS), Pohang, 790–784, Republic of Korea

^bDepartment of Chemistry, Pohang University of Science and Technology (POSTECH), Pohang, 790–784, Republic of Korea eMail: eslee@postech.ac.kr

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Abstract

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Abstract

The transition-metal-like behavior of N-heterocyclic carbenes (NHCs) in the activation of small molecules such as CO, NO, N₂O, H₂, and NH₃ is reviewed. The resemblance to transition metals is mainly attributed to the adjustable electronic properties of the carbene centers through modification of their structure. Furthermore, applications of NHCs in the activation of various C–H bonds for functionalization are explored.

Key words

N-heterocyclic carbine - main-group chemistry - small-molecule activation - radical chemistry - C–H bond activation

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Referenzen

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