Simple Solubilization of the Traditional 2,2′:6′,2′′-Terpyridine Ligand­ in Organic Solvents by Substitution with 4,4′′-Di-tert-butyl Groups

Baptiste Laramée-Milette; Thomas Auvray; Sacha Nguyen; Samantha Tremblay; Christophe Lachance-Brais; Mélanie Donguy; Valeska Taylor; Denis Deschênes; Garry S. Hanan

doi:10.1055/s-0035-1560324

Synthesis, Inhaltsverzeichnis

Synthesis 2015; 47(24): 3849-3858
DOI: 10.1055/s-0035-1560324

paper

Simple Solubilization of the Traditional 2,2′:6′,2′′-Terpyridine Ligand in Organic Solvents by Substitution with 4,4′′-Di-tert-butyl Groups

Baptiste Laramée-Milette

^aDépartement de Chimie, Pavillon J.-A. Bombardier, 5155 Chemin de la Rampe, Université de Montréal, Montréal, Québec, H3T 2B1, Canada eMail: garry.hanan@umontreal.ca

,

Thomas Auvray

^aDépartement de Chimie, Pavillon J.-A. Bombardier, 5155 Chemin de la Rampe, Université de Montréal, Montréal, Québec, H3T 2B1, Canada eMail: garry.hanan@umontreal.ca

,

Sacha Nguyen

^aDépartement de Chimie, Pavillon J.-A. Bombardier, 5155 Chemin de la Rampe, Université de Montréal, Montréal, Québec, H3T 2B1, Canada eMail: garry.hanan@umontreal.ca

^bDépartement de Chimie, 1 Rue de la Technologie, UT Lyon 1, 69622 Villeurbanne cedex, France

,

Samantha Tremblay

^aDépartement de Chimie, Pavillon J.-A. Bombardier, 5155 Chemin de la Rampe, Université de Montréal, Montréal, Québec, H3T 2B1, Canada eMail: garry.hanan@umontreal.ca

,

Christophe Lachance-Brais

^aDépartement de Chimie, Pavillon J.-A. Bombardier, 5155 Chemin de la Rampe, Université de Montréal, Montréal, Québec, H3T 2B1, Canada eMail: garry.hanan@umontreal.ca

,

Mélanie Donguy

^aDépartement de Chimie, Pavillon J.-A. Bombardier, 5155 Chemin de la Rampe, Université de Montréal, Montréal, Québec, H3T 2B1, Canada eMail: garry.hanan@umontreal.ca

^bDépartement de Chimie, 1 Rue de la Technologie, UT Lyon 1, 69622 Villeurbanne cedex, France

,

Valeska Taylor

^aDépartement de Chimie, Pavillon J.-A. Bombardier, 5155 Chemin de la Rampe, Université de Montréal, Montréal, Québec, H3T 2B1, Canada eMail: garry.hanan@umontreal.ca

,

Denis Deschênes

^aDépartement de Chimie, Pavillon J.-A. Bombardier, 5155 Chemin de la Rampe, Université de Montréal, Montréal, Québec, H3T 2B1, Canada eMail: garry.hanan@umontreal.ca

,

Garry S. Hanan*

^aDépartement de Chimie, Pavillon J.-A. Bombardier, 5155 Chemin de la Rampe, Université de Montréal, Montréal, Québec, H3T 2B1, Canada eMail: garry.hanan@umontreal.ca

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Abstract

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Abstract

A simple one-pot procedure is described for the synthesis and purification of 4′-substituted 4,4′′-di-tert-butyl-2,2′:6′,2′′-terpyridine ligands. The new series of ligand display improved solubility in most organic solvents in comparison to traditional 2,2′:6′,2′′-terpyridine ligands.

Key words

terpyridine - tert-butyl - tridentate ligand - one-pot synthesis - coordination chemistry

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Referenzen

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Supporting Information

Simple Solubilization of the Traditional 2,2′:6′,2′′-Terpyridine Ligand­ in Organic Solvents by Substitution with 4,4′′-Di-tert-butyl Groups

Simple Solubilization of the Traditional 2,2′:6′,2′′-Terpyridine Ligand in Organic Solvents by Substitution with 4,4′′-Di-tert-butyl Groups