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Synthesis 2015; 47(07): 969-975
DOI: 10.1055/s-0034-1379972
DOI: 10.1055/s-0034-1379972
paper
Synthesis of β-Trifluoromethylthio- and β-Trifluoromethylseleno-α,β-unsaturated Ketones through Copper-Mediated Trifluoromethylthio(seleno)lation
Further Information
Publication History
Received: 29 September 2012
Accepted after revision: 11 December 2014
Publication Date:
22 January 2015 (online)
Abstract
An efficient and convenient synthetic methodology has been developed with which to construct β-trifluoromethylthio- and seleno-α,β-unsaturated ketones through copper-mediated trifluoromethylthio(seleno)lation of β-bromo α,β-unsaturated ketones. The corresponding ketone products were isolated in moderate to good yields and were efficiently converted into valuable alcohols.
Supporting Information
- Supporting information for this article is available online at http://dx.doi.org/10.1055/s-0034–1379972.
- Supporting Information
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