Activated Cyclopropanes: A Remarkable Breadth of Recent Chemistry

James R. Green; Victor Snieckus

doi:10.1055/s-0034-1379212

Synlett, Inhaltsverzeichnis

Synlett 2014; 25(16): 2258-2259
DOI: 10.1055/s-0034-1379212

cluster

Activated Cyclopropanes: A Remarkable Breadth of Recent Chemistry

James R. Green*

^aDepartment of Chemistry and Biochemistry, University of Windsor, Windsor, ON, N9B 3P4, Canada eMail: jgreen@uwindsor.ca

,

Victor Snieckus*

^bDepartment of Chemistry, Queen’s University, Kingston, ON, K7L 3N6, Canada eMail: Victor.Snieckus@chem.queensu.ca

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Abstract

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Abstract

The reactions of cyclopropanes activated by electron-withdrawing groups and electron-donating groups – donor–acceptor (DA) cyclopropanes – and with alkenyl or alkylidene substituents has been an area of recent intense research activity. This Cluster contains contributions from many of the leading research groups in this area, and provides a concise introduction to the rich ring-opening, ring-expansion, dimerization, and cycloaddition chemistry of these compounds.

Key words

cyclopropanes - ring opening - cycloaddition - rearrangement - Lewis acids - catalysis

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Referenzen

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