Catalytic Asymmetric Hydrosilylation of 1,1-Disubstituted Alkenes

Abstract

Catalytic asymmetric hydrosilylation of 1,1-disubstituted alkenes has been summarized. The intramolecular reactions proceed efficiently in the presence of noble transition-metal rhodium. The highly enantioselective intermolecular processes are catalyzed by earth-abundant transition-metal iron.

Key words

asymmetric catalysis - alkene - iron - rhodium - hydrosilylation

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