Suzuki and Stille Cross-Coupling Reactions from β-Iodovinylphosphonate: Stereoselective Access to Various Substituted Vinylphosphonates

Emilie Thiery; Mohamed Abarbri

doi:10.1055/s-0034-1378360

Synthesis, Table of Contents

Synthesis 2014; 46(20): 2757-2762
DOI: 10.1055/s-0034-1378360

paper

Suzuki and Stille Cross-Coupling Reactions from β-Iodovinylphosphonate: Stereoselective Access to Various Substituted Vinylphosphonates

Emilie Thiery

Laboratoire d’Infectiologie et Santé Publique (UMR Université François Rabelais/INRA 1282), Université François Rabelais, Faculté des Sciences, Parc de Grandmont, 37200 Tours, France Fax: +33(2)47367073 Email: mohamed.abarbri@univ-tours.fr

,

Mohamed Abarbri*

Laboratoire d’Infectiologie et Santé Publique (UMR Université François Rabelais/INRA 1282), Université François Rabelais, Faculté des Sciences, Parc de Grandmont, 37200 Tours, France Fax: +33(2)47367073 Email: mohamed.abarbri@univ-tours.fr

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Abstract

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Abstract

Stereoselective synthesis of β-arylvinyl, dienyl, and enynylphosphonates was achieved from diethyl 2-iodovinylphosphonate via Suzuki or Stille cross-coupling reactions in good yields.

Key words

cross-coupling - stereoselective - arylvinylphosphonates - dienylphosphonates - enynylphosphonates

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References

References

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