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Synlett 2014; 25(10): 1458-1460
DOI: 10.1055/s-0033-1341243
DOI: 10.1055/s-0033-1341243
letter
Copper-Catalyzed Aerobic Oxidative C–C Bond Cleavage of 1,3-Diaryldiketones To Synthesize 1,2-Diketones
Authors
Further Information
Publication History
Received: 12 February 2014
Accepted after revision: 25 March 2014
Publication Date:
08 May 2014 (online)
Abstract
An aerobic oxidative C–C bond cleavage of 1,3-diaryldiketones for the synthesis of 1,2-diketones by using O2 as the oxidant has been developed. Control experiments illustrate that the copper catalyst not only assist the aerobic oxidative process of 1,3-diketones, but also catalyze the 1,2-Wagner–Meerwein-type rearrangement process.
Supporting Information
- for this article is available online at http://www.thieme-connect.com/products/ejournals/journal/
10.1055/s-00000083.
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For some selected reviews about copper-catalyzed aerobic oxidative dehydrogenative coupling reaction in the last three years, see:
For some selected examples about copper-catalyzed aerobic oxidative dehydrogenative coupling reaction in the last three years, see: