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Synlett 2014; 25(4): 523-526
DOI: 10.1055/s-0033-1340552
DOI: 10.1055/s-0033-1340552
letter
Zn(OTf)2-Catalyzed Glycosylation of Glycals: Synthesis of 2,3-Unsaturated Glycosides via a Ferrier Reaction
Authors
Further Information
Publication History
Received: 07 November 2013
Accepted after revision: 09 December 2013
Publication Date:
14 January 2014 (online)
Abstract
A mild, catalytic, and efficient protocol has been developed for the synthesis of 2,3-unsaturated glycosides or ‘pseudo-glycals’ using Zn(OTf)2. Stereoselective glycosylation of glycal donor with various acceptors comprising of alcohols, phenols, thiols, and sugar aglycones proceeds smoothly to afford the corresponding 2,3-unsaturaed glycosides in good to excellent yields.
Supporting Information
- for this article is available online at http://www.thieme-connect.com/ejournals/toc/synlett.
- Supporting Information (PDF)
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