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Synthesis 2014; 46(05): 653-659
DOI: 10.1055/s-0033-1340497
DOI: 10.1055/s-0033-1340497
paper
Synthesis of Functional Tripodal Phosphines with Amino and Ether Groups by the Hydrophosphination of Trivinyl Ethers with Secondary Phosphines
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Publication History
Received: 17 October 2013
Accepted after revision: 09 December 2013
Publication Date:
08 January 2014 (online)
Abstract
A one-pot, atom-economic, metal- and halogen-free synthesis of functional triphosphines with nitrogen and (or) oxygen atoms as additional weaker coordinating sites (new hemilabile ligands) through exhaustive addition of secondary phosphines to available trivinyl ethers of aminotriols and triols has been developed. The reaction proceeds under free-radical conditions (UV irradiation or AIBN, with 3:1 reactant molar ratio) to give chemo- and regioselectively anti-Markovnikov triadducts to all three vinyloxy groups in good to excellent yields.
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