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Synlett 2014; 25(13): 1901-1903
DOI: 10.1055/s-0033-1340187
DOI: 10.1055/s-0033-1340187
letter
Reductive Passerini/Tsuji–Trost Strategy towards β,γ-Unsaturated Amides
Further Information
Publication History
Received 17 April 2014
Accepted after revision: 30 April 2014
Publication Date:
03 June 2014 (online)
Abstract
The Passerini reaction of α,β-unsaturated aldehydes with formic acid followed by a reductive Tsuji–Trost reaction affords β,γ-unsaturated amides. The overall process may be viewed as a one-carbon homologation of unsaturated aldehydes into amides.
Supporting Information
- for this article is available online at http://www.thieme-connect.com/products/ejournals/journal/ 10.1055/s-00000083.
- Supporting Information
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For recent reviews, see:
For reviews on Tsuji–Trost reactions, see