Differentiated Di- and Polyboron Compounds: Synthesis and Application in Successive Suzuki–Miyaura Coupling

Liang Xu; Pengfei Li

doi:10.1055/s-0033-1339114

Synlett, Table of Contents

Synlett 2014; 25(13): 1799-1802
DOI: 10.1055/s-0033-1339114

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Differentiated Di- and Polyboron Compounds: Synthesis and Application in Successive Suzuki–Miyaura Coupling

Liang Xu

Center for Organic Chemistry, Frontier Institute of Science and Technology (FIST) and Frontier Institute of Chemistry, Xi’an Jiaotong University, 99 Yanxiang Road, Xi’an, Shaanxi 710054, P. R. of China Fax: +86(29)83395132 Email: lipengfei@mail.xjtu.edu.cn

,

Pengfei Li*

Center for Organic Chemistry, Frontier Institute of Science and Technology (FIST) and Frontier Institute of Chemistry, Xi’an Jiaotong University, 99 Yanxiang Road, Xi’an, Shaanxi 710054, P. R. of China Fax: +86(29)83395132 Email: lipengfei@mail.xjtu.edu.cn

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Abstract

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Abstract

Differentiated polyboron compounds have emerged as powerful building blocks for modular assembly of complex molecules through selective Suzuki–Miyaura coupling (SMC). Recent progress in this area is briefly reviewed. A novel methodology involving iridium-catalyzed C–H borylation and highly selective SMC toward synthesis and application of this type of building blocks is discussed.

Key words

polyboron - selective coupling - C–H borylation - modular synthesis

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References

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