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Synthesis 2013; 45(5): 615-620
DOI: 10.1055/s-0032-1318172
DOI: 10.1055/s-0032-1318172
paper
Co(acac)2-Catalyzed Allylic and Benzylic Oxidation by tert-Butyl Hydroperoxide
Further Information
Publication History
Received: 19 November 2012
Accepted after revision: 18 January 2013
Publication Date:
01 February 2013 (online)
Abstract
Various allylic and benzylic substrates were oxidized to the corresponding enones, arenealdehydes and aryl ketones in good yields with tert-butyl hydroperoxide in the presence of catalytic amounts of Co(acac)2 under mild conditions. The reactivity, selectivity, and scope of the reaction were investigated.
Key words
Co(acac)2 - allylic and benzylic oxidation - tert-butyl hydroperoxide - enones - benzaldehydes - ketonesSupporting Information
- for this article is available online at http://www.thieme-connect.com/ejournals/toc/synthesis.
- Supporting Information
-
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