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Synthesis 2013; 45(7): 966-970
DOI: 10.1055/s-0032-1316863
DOI: 10.1055/s-0032-1316863
paper
Regioselective Synthesis of Phenoxathiin Derivatives under Transition-Metal-Free Conditions
Further Information
Publication History
Received: 30 December 2012
Accepted after revision: 06 February 2013
Publication Date:
28 February 2013 (online)
Abstract
A simple and efficient method was developed for the synthesis of phenoxathiin derivatives. A range of 1,2-dihaloarenes or 1-halo-2-nitroarenes reacted with 2-sulfanylphenol to give the desired products in good-to-excellent yields. It is intriguing that 1-halo-2-nitroarenes containing electron-donating groups worked well as substrates in this reaction.
Supporting Information
- for this article is available online at http://www.thieme-connect.com/ejournals/toc/synthesis.
- Supporting Information
Primary Data
- for this article are available online at http://www.thieme-connect.com/ejournals/toc/synthesis and can be cited using the following DOI: 10.4125/pd0042th
- Primary Data
-
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