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Synthesis 2013; 45(2): 183-188
DOI: 10.1055/s-0032-1316824
DOI: 10.1055/s-0032-1316824
paper
Facile Preparation of Unsymmetrical Diaryl Ethers from Unsymmetrical Diaryliodonium Tosylates and Phenols with High Regioselectivity
Authors
Weitere Informationen
Publikationsverlauf
Received: 10. Oktober 2012
Accepted after revision: 13. November 2012
Publikationsdatum:
30. November 2012 (online)
Abstract
Unsymmetrical diaryl ethers were efficiently obtained in good yields by the reactions of aryl(4-methoxyphenyl)iodonium tosylates with phenols, and aryl(2,4-dimethoxyphenyl)iodonium tosylates with phenols, in the presence of potassium carbonate in acetonitrile, respectively. The latter iodonium tosylates provided the corresponding unsymmetrical diaryl ethers in good yields with high regioselectivities, together with the quantitative formation of 1-iodo-2,4-dimethoxybenzene.
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