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Synthesis 2012; 44(18): 2903-2909
DOI: 10.1055/s-0032-1316747
DOI: 10.1055/s-0032-1316747
paper
A Simple and Effective Synthesis of Benzolactones and Benzolactams by Noncatalytic Benzylic Oxidation of Cyclic Benzylic Ethers and N-Protected Cyclic Benzylic Amines with Sodium Chlorite as an Oxidant
Further Information
Publication History
Received: 04 May 2012
Accepted after revision: 20 June 2012
Publication Date:
30 July 2012 (online)
Abstract
Sodium chlorite (NaClO2) was shown to be capable of oxidizing cyclic benzylic ethers and N-protected cyclic benzylic amines in a heterogeneous solvent system of 1,1,1-trichloroethane and water at 55–65 °C to give synthetically useful benzolactones and benzolactams, respectively, in high-to-excellent yields.
Supporting Information
- for this article is available online at http://www.thieme-connect.com/ejournals/toc/synthesis.
- Supporting Information
-
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