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Synthesis 2012; 44(11): 1631-1636
DOI: 10.1055/s-0031-1290972
DOI: 10.1055/s-0031-1290972
paper
Regioselective Synthesis of Trialkylpyrazines via Nickel-Catalyzed Negishi Cross-Coupling of Pyrazine Triflate
Further Information
Publication History
Received: 05 March 2012
Accepted after revision: 28 March 2012
Publication Date:
08 May 2012 (online)
Abstract
A regioselective synthesis of trialkylpyrazines via nickel-catalyzed cross-coupling reaction of pyrazine triflate is reported. The 5-substituted 2,3-dimethylpyrazine derivatives including trail pheromone components of the ant Eutetramorium mocquerysi have been successfully synthesized in good yields by nickel-catalyzed Negishi cross-coupling reactions of pyrazine triflate mediated by alkyl and arylzinc halides.
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