Synlett 2012; 23(9): 1335-1338
DOI: 10.1055/s-0031-1290958
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© Georg Thieme Verlag Stuttgart · New York

Direct Synthesis of Organic Azides from Alcohols Using 2-Azido-1,3-dimethyl­imidazolinium Hexafluorophosphate

Mitsuru Kitamura*
Department of Applied Chemistry, Kyushu Institute of Technology, 1-1 Sensuicho, Tobata, Kitakyushu 804-8550, Japan, Fax: +81(93)8843304   eMail: kita@che.kyutech.ac.jp
,
Tatsuya Koga
Department of Applied Chemistry, Kyushu Institute of Technology, 1-1 Sensuicho, Tobata, Kitakyushu 804-8550, Japan, Fax: +81(93)8843304   eMail: kita@che.kyutech.ac.jp
,
Masakazu Yano
Department of Applied Chemistry, Kyushu Institute of Technology, 1-1 Sensuicho, Tobata, Kitakyushu 804-8550, Japan, Fax: +81(93)8843304   eMail: kita@che.kyutech.ac.jp
,
Tatsuo Okauchi
Department of Applied Chemistry, Kyushu Institute of Technology, 1-1 Sensuicho, Tobata, Kitakyushu 804-8550, Japan, Fax: +81(93)8843304   eMail: kita@che.kyutech.ac.jp
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Publikationsverlauf

Received: 22. Februar 2012

Accepted after revision: 13. März 2012

Publikationsdatum:
14. Mai 2012 (online)


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Abstract

Direct synthesis of organic azides from alcohols was developed. Azide transfer of 2-azido-1,3-dimethylimidazolinium hexafluorophosphate (ADMP) to alcohols proceeds to give the corresponding azides under mild reaction conditions, which were easily isolated because the byproducts are highly soluble in water.